Kinetic thermal analysis of glass ceramics from industrial wastes
To recycle inorganic industrial solid wastes, the use of glass ceramics has been proposed as a useful choice. In this work, a pyroxene glass ceramic of the CaO–MgO–Al 2O 3–SiO 2 family was synthesized by mixing three industrial wastes of high production rate generated in northeast Mexico. A kinetic...
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Veröffentlicht in: | Journal of non-crystalline solids 2003-11, Vol.329 (1), p.73-76 |
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container_title | Journal of non-crystalline solids |
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creator | Alvarez-Méndez, A. Torres-González, L.C. Alvarez, N. Torres-Martı́ nez, L.M. |
description | To recycle inorganic industrial solid wastes, the use of glass ceramics has been proposed as a useful choice. In this work, a pyroxene glass ceramic of the CaO–MgO–Al
2O
3–SiO
2 family was synthesized by mixing three industrial wastes of high production rate generated in northeast Mexico. A kinetic study was carried out by a non-isothermal differential thermal analysis technique (DTA) from which the kinetic parameters, activation energy for crystallization,
E
a, of 534
±
4 kJ
mol
−1, frequency factor,
ν, of 5.60
×
10
20 min
−1 and Avrami factor,
n, values between 1.2
±
0.2 and 1.3
±
0.1 were estimated, corresponding to a surface crystallization mechanism. |
doi_str_mv | 10.1016/j.jnoncrysol.2003.08.017 |
format | Article |
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2O
3–SiO
2 family was synthesized by mixing three industrial wastes of high production rate generated in northeast Mexico. A kinetic study was carried out by a non-isothermal differential thermal analysis technique (DTA) from which the kinetic parameters, activation energy for crystallization,
E
a, of 534
±
4 kJ
mol
−1, frequency factor,
ν, of 5.60
×
10
20 min
−1 and Avrami factor,
n, values between 1.2
±
0.2 and 1.3
±
0.1 were estimated, corresponding to a surface crystallization mechanism.</description><identifier>ISSN: 0022-3093</identifier><identifier>EISSN: 1873-4812</identifier><identifier>DOI: 10.1016/j.jnoncrysol.2003.08.017</identifier><identifier>CODEN: JNCSBJ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; Materials science ; Materials testing ; Physics ; Thermal analysis, differential thermal analysis (DTA), differential thermogravimetric analysis</subject><ispartof>Journal of non-crystalline solids, 2003-11, Vol.329 (1), p.73-76</ispartof><rights>2003 Elsevier B.V.</rights><rights>2004 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c484t-c208ddbe1f40575a9bdbe769e956dce18ed4c6f5561e304bbf752b844c41d2ae3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jnoncrysol.2003.08.017$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>309,310,314,780,784,789,790,3550,23930,23931,25140,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15272723$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Alvarez-Méndez, A.</creatorcontrib><creatorcontrib>Torres-González, L.C.</creatorcontrib><creatorcontrib>Alvarez, N.</creatorcontrib><creatorcontrib>Torres-Martı&#x0301;nez, L.M.</creatorcontrib><title>Kinetic thermal analysis of glass ceramics from industrial wastes</title><title>Journal of non-crystalline solids</title><description>To recycle inorganic industrial solid wastes, the use of glass ceramics has been proposed as a useful choice. In this work, a pyroxene glass ceramic of the CaO–MgO–Al
2O
3–SiO
2 family was synthesized by mixing three industrial wastes of high production rate generated in northeast Mexico. A kinetic study was carried out by a non-isothermal differential thermal analysis technique (DTA) from which the kinetic parameters, activation energy for crystallization,
E
a, of 534
±
4 kJ
mol
−1, frequency factor,
ν, of 5.60
×
10
20 min
−1 and Avrami factor,
n, values between 1.2
±
0.2 and 1.3
±
0.1 were estimated, corresponding to a surface crystallization mechanism.</description><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Materials science</subject><subject>Materials testing</subject><subject>Physics</subject><subject>Thermal analysis, differential thermal analysis (DTA), differential thermogravimetric analysis</subject><issn>0022-3093</issn><issn>1873-4812</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNqFkMtOwzAQRS0EEqXwD97ALsF2nNhdloqXqMQG1pZjT8BRHsWTgvr3uGollswsRiOdO1dzCaGc5Zzx6rbN22EcXNzh2OWCsSJnOmdcnZAZ16rIpObilMwYEyIr2KI4JxeILUulCj0jy5cwwBQcnT4h9rajdrDdDgPSsaEfnUWkDqLtg0PaxLGnYfBbnGJI6I_FCfCSnDW2Q7g6zjl5f7h_Wz1l69fH59VynTmp5ZQ5wbT3NfBGslKVdlGnRVULWJSVd8A1eOmqpiwrDgWTdd2oUtRaSie5FxaKObk53N3E8WsLOJk-oIOuswOMWzRCaSE05wnUB9DFETFCYzYx9DbuDGdmn5lpzV9mZp-ZYdqkzJL0-uhh0dmuiXZwAf_0pVCpi8TdHThID38HiAZdgMGBDxHcZPwY_jf7BdTdiQc</recordid><startdate>20031101</startdate><enddate>20031101</enddate><creator>Alvarez-Méndez, A.</creator><creator>Torres-González, L.C.</creator><creator>Alvarez, N.</creator><creator>Torres-Martı&#x0301;nez, L.M.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20031101</creationdate><title>Kinetic thermal analysis of glass ceramics from industrial wastes</title><author>Alvarez-Méndez, A. ; Torres-González, L.C. ; Alvarez, N. ; Torres-Martı&#x0301;nez, L.M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c484t-c208ddbe1f40575a9bdbe769e956dce18ed4c6f5561e304bbf752b844c41d2ae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>Materials science</topic><topic>Materials testing</topic><topic>Physics</topic><topic>Thermal analysis, differential thermal analysis (DTA), differential thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Alvarez-Méndez, A.</creatorcontrib><creatorcontrib>Torres-González, L.C.</creatorcontrib><creatorcontrib>Alvarez, N.</creatorcontrib><creatorcontrib>Torres-Martı&#x0301;nez, L.M.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of non-crystalline solids</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Alvarez-Méndez, A.</au><au>Torres-González, L.C.</au><au>Alvarez, N.</au><au>Torres-Martı&#x0301;nez, L.M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetic thermal analysis of glass ceramics from industrial wastes</atitle><jtitle>Journal of non-crystalline solids</jtitle><date>2003-11-01</date><risdate>2003</risdate><volume>329</volume><issue>1</issue><spage>73</spage><epage>76</epage><pages>73-76</pages><issn>0022-3093</issn><eissn>1873-4812</eissn><coden>JNCSBJ</coden><abstract>To recycle inorganic industrial solid wastes, the use of glass ceramics has been proposed as a useful choice. In this work, a pyroxene glass ceramic of the CaO–MgO–Al
2O
3–SiO
2 family was synthesized by mixing three industrial wastes of high production rate generated in northeast Mexico. A kinetic study was carried out by a non-isothermal differential thermal analysis technique (DTA) from which the kinetic parameters, activation energy for crystallization,
E
a, of 534
±
4 kJ
mol
−1, frequency factor,
ν, of 5.60
×
10
20 min
−1 and Avrami factor,
n, values between 1.2
±
0.2 and 1.3
±
0.1 were estimated, corresponding to a surface crystallization mechanism.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jnoncrysol.2003.08.017</doi><tpages>4</tpages></addata></record> |
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subjects | Cross-disciplinary physics: materials science rheology Exact sciences and technology Materials science Materials testing Physics Thermal analysis, differential thermal analysis (DTA), differential thermogravimetric analysis |
title | Kinetic thermal analysis of glass ceramics from industrial wastes |
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