Kinetic thermal analysis of glass ceramics from industrial wastes

To recycle inorganic industrial solid wastes, the use of glass ceramics has been proposed as a useful choice. In this work, a pyroxene glass ceramic of the CaO–MgO–Al 2O 3–SiO 2 family was synthesized by mixing three industrial wastes of high production rate generated in northeast Mexico. A kinetic...

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Veröffentlicht in:Journal of non-crystalline solids 2003-11, Vol.329 (1), p.73-76
Hauptverfasser: Alvarez-Méndez, A., Torres-González, L.C., Alvarez, N., Torres-Martı&#x0301, nez, L.M.
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container_end_page 76
container_issue 1
container_start_page 73
container_title Journal of non-crystalline solids
container_volume 329
creator Alvarez-Méndez, A.
Torres-González, L.C.
Alvarez, N.
Torres-Martı&#x0301
nez, L.M.
description To recycle inorganic industrial solid wastes, the use of glass ceramics has been proposed as a useful choice. In this work, a pyroxene glass ceramic of the CaO–MgO–Al 2O 3–SiO 2 family was synthesized by mixing three industrial wastes of high production rate generated in northeast Mexico. A kinetic study was carried out by a non-isothermal differential thermal analysis technique (DTA) from which the kinetic parameters, activation energy for crystallization, E a, of 534 ± 4 kJ mol −1, frequency factor, ν, of 5.60 × 10 20 min −1 and Avrami factor, n, values between 1.2 ± 0.2 and 1.3 ± 0.1 were estimated, corresponding to a surface crystallization mechanism.
doi_str_mv 10.1016/j.jnoncrysol.2003.08.017
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subjects Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Materials testing
Physics
Thermal analysis, differential thermal analysis (DTA), differential thermogravimetric analysis
title Kinetic thermal analysis of glass ceramics from industrial wastes
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