Concurrent surface enhanced infrared and Raman spectroscopy with single molecule sensitivity
Surface enhanced infrared absorption (SEIRA) and surface enhanced Raman Spectroscopy (SERS) were simultaneously measured from the same location on plasmonically active substrates. The spectra were acquired using an optical photothermal infrared spectrometer coupled with a Raman spectrometer. The sen...
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| Veröffentlicht in: | Review of scientific instruments 2023-02, Vol.94 (2), p.025103-025103 |
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| creator | Anderson, Mark S. |
| description | Surface enhanced infrared absorption (SEIRA) and surface enhanced Raman Spectroscopy (SERS) were simultaneously measured from the same location on plasmonically active substrates. The spectra were acquired using an optical photothermal infrared spectrometer coupled with a Raman spectrometer. The sensitivity of this approach enables exceptionally small quantities of molecules to be interrogated while providing complementary information from both infrared and Raman spectroscopy. This arrangement provides additional improvement of SEIRA through the enhancement of both the optical photothermal detector signal and the infrared absorption. The plasmonic substrates tested were silver nanospheres and a gold coated atomic force microscope tip. The concurrent acquisition of SEIRA and SERS is further demonstrated by nano-sampling material onto an atomic force microscope tip. The analytes, Buckminsterfullerene and 1,2-bis(4-pyridyl) ethylene, were analyzed individually and as mixtures. The concurrent acquisition of SERIA and SERS is a unique approach. It has general applications in trace surface analysis and for the analysis of returned planetary samples. |
| doi_str_mv | 10.1063/5.0136908 |
| format | Article |
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The spectra were acquired using an optical photothermal infrared spectrometer coupled with a Raman spectrometer. The sensitivity of this approach enables exceptionally small quantities of molecules to be interrogated while providing complementary information from both infrared and Raman spectroscopy. This arrangement provides additional improvement of SEIRA through the enhancement of both the optical photothermal detector signal and the infrared absorption. The plasmonic substrates tested were silver nanospheres and a gold coated atomic force microscope tip. The concurrent acquisition of SEIRA and SERS is further demonstrated by nano-sampling material onto an atomic force microscope tip. The analytes, Buckminsterfullerene and 1,2-bis(4-pyridyl) ethylene, were analyzed individually and as mixtures. The concurrent acquisition of SERIA and SERS is a unique approach. It has general applications in trace surface analysis and for the analysis of returned planetary samples.</description><identifier>ISSN: 0034-6748</identifier><identifier>EISSN: 1089-7623</identifier><identifier>DOI: 10.1063/5.0136908</identifier><identifier>PMID: 36859062</identifier><identifier>CODEN: RSINAK</identifier><language>eng</language><publisher>United States: American Institute of Physics</publisher><subject>Atomic force microscopes ; Buckminsterfullerene ; Gold coatings ; Infrared absorption ; Infrared radiation ; Infrared spectrometers ; Infrared spectroscopy ; Nanospheres ; Optical communication ; Raman spectroscopy ; Sensitivity enhancement ; Silver ; Spectrum analysis ; Substrates ; Surface analysis (chemical) ; Surface chemistry</subject><ispartof>Review of scientific instruments, 2023-02, Vol.94 (2), p.025103-025103</ispartof><rights>Author(s)</rights><rights>2023 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c348t-8b54884a01b8fc447bd75c30a3ed7c5a2ee5e6b0e502bc1d25b89c6fec9f01613</citedby><cites>FETCH-LOGICAL-c348t-8b54884a01b8fc447bd75c30a3ed7c5a2ee5e6b0e502bc1d25b89c6fec9f01613</cites><orcidid>0000-0001-7776-4402</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/rsi/article-lookup/doi/10.1063/5.0136908$$EHTML$$P50$$Gscitation$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,794,4512,27924,27925,76384</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36859062$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Anderson, Mark S.</creatorcontrib><title>Concurrent surface enhanced infrared and Raman spectroscopy with single molecule sensitivity</title><title>Review of scientific instruments</title><addtitle>Rev Sci Instrum</addtitle><description>Surface enhanced infrared absorption (SEIRA) and surface enhanced Raman Spectroscopy (SERS) were simultaneously measured from the same location on plasmonically active substrates. The spectra were acquired using an optical photothermal infrared spectrometer coupled with a Raman spectrometer. The sensitivity of this approach enables exceptionally small quantities of molecules to be interrogated while providing complementary information from both infrared and Raman spectroscopy. This arrangement provides additional improvement of SEIRA through the enhancement of both the optical photothermal detector signal and the infrared absorption. The plasmonic substrates tested were silver nanospheres and a gold coated atomic force microscope tip. The concurrent acquisition of SEIRA and SERS is further demonstrated by nano-sampling material onto an atomic force microscope tip. The analytes, Buckminsterfullerene and 1,2-bis(4-pyridyl) ethylene, were analyzed individually and as mixtures. The concurrent acquisition of SERIA and SERS is a unique approach. It has general applications in trace surface analysis and for the analysis of returned planetary samples.</description><subject>Atomic force microscopes</subject><subject>Buckminsterfullerene</subject><subject>Gold coatings</subject><subject>Infrared absorption</subject><subject>Infrared radiation</subject><subject>Infrared spectrometers</subject><subject>Infrared spectroscopy</subject><subject>Nanospheres</subject><subject>Optical communication</subject><subject>Raman spectroscopy</subject><subject>Sensitivity enhancement</subject><subject>Silver</subject><subject>Spectrum analysis</subject><subject>Substrates</subject><subject>Surface analysis (chemical)</subject><subject>Surface chemistry</subject><issn>0034-6748</issn><issn>1089-7623</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp90E9L5DAYBvAgis6qB7-AFLy4QjVp_jQ9yuCugiCI3oSSpm_XSJvUJFXm25thxhFWMJe8hx9P8j4IHRF8TrCgF_wcEyoqLLfQjGBZ5aUo6DaaYUxZLkom99CvEF5wOpyQXbRHheQVFsUMPc2d1ZP3YGMWJt8pDRnYZ2U1tJmxnVc-Dcq22b0alM3CCDp6F7QbF9m7ic9ZMPZfD9ngetBTGgLYYKJ5M3FxgHY61Qc4XN_76PHP1cP8Or-9-3szv7zNNWUy5rLhTEqmMGlkpxkrm7bkmmJFoS01VwUAB9Fg4LhoNGkL3shKiw501WEiCN1Hp6vc0bvXCUKsBxM09L2y4KZQF6UkoiiI4Ime_Edf3ORt-l1SJROSML4M_L1SOq0aPHT16M2g_KImuF5WXvN6XXmyx-vEqRmg3cjPjhM4W4GgTVTROLsxb85_JdVj2_2Evz_9AfcgmFI</recordid><startdate>20230201</startdate><enddate>20230201</enddate><creator>Anderson, Mark S.</creator><general>American Institute of Physics</general><scope>AJDQP</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-7776-4402</orcidid></search><sort><creationdate>20230201</creationdate><title>Concurrent surface enhanced infrared and Raman spectroscopy with single molecule sensitivity</title><author>Anderson, Mark S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c348t-8b54884a01b8fc447bd75c30a3ed7c5a2ee5e6b0e502bc1d25b89c6fec9f01613</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Atomic force microscopes</topic><topic>Buckminsterfullerene</topic><topic>Gold coatings</topic><topic>Infrared absorption</topic><topic>Infrared radiation</topic><topic>Infrared spectrometers</topic><topic>Infrared spectroscopy</topic><topic>Nanospheres</topic><topic>Optical communication</topic><topic>Raman spectroscopy</topic><topic>Sensitivity enhancement</topic><topic>Silver</topic><topic>Spectrum analysis</topic><topic>Substrates</topic><topic>Surface analysis (chemical)</topic><topic>Surface chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Anderson, Mark S.</creatorcontrib><collection>AIP Open Access Journals</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Review of scientific instruments</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Anderson, Mark S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Concurrent surface enhanced infrared and Raman spectroscopy with single molecule sensitivity</atitle><jtitle>Review of scientific instruments</jtitle><addtitle>Rev Sci Instrum</addtitle><date>2023-02-01</date><risdate>2023</risdate><volume>94</volume><issue>2</issue><spage>025103</spage><epage>025103</epage><pages>025103-025103</pages><issn>0034-6748</issn><eissn>1089-7623</eissn><coden>RSINAK</coden><abstract>Surface enhanced infrared absorption (SEIRA) and surface enhanced Raman Spectroscopy (SERS) were simultaneously measured from the same location on plasmonically active substrates. The spectra were acquired using an optical photothermal infrared spectrometer coupled with a Raman spectrometer. The sensitivity of this approach enables exceptionally small quantities of molecules to be interrogated while providing complementary information from both infrared and Raman spectroscopy. This arrangement provides additional improvement of SEIRA through the enhancement of both the optical photothermal detector signal and the infrared absorption. The plasmonic substrates tested were silver nanospheres and a gold coated atomic force microscope tip. The concurrent acquisition of SEIRA and SERS is further demonstrated by nano-sampling material onto an atomic force microscope tip. The analytes, Buckminsterfullerene and 1,2-bis(4-pyridyl) ethylene, were analyzed individually and as mixtures. The concurrent acquisition of SERIA and SERS is a unique approach. It has general applications in trace surface analysis and for the analysis of returned planetary samples.</abstract><cop>United States</cop><pub>American Institute of Physics</pub><pmid>36859062</pmid><doi>10.1063/5.0136908</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-7776-4402</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | Review of scientific instruments, 2023-02, Vol.94 (2), p.025103-025103 |
| issn | 0034-6748 1089-7623 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2781622165 |
| source | American Institute of Physics (AIP) Journals; Alma/SFX Local Collection |
| subjects | Atomic force microscopes Buckminsterfullerene Gold coatings Infrared absorption Infrared radiation Infrared spectrometers Infrared spectroscopy Nanospheres Optical communication Raman spectroscopy Sensitivity enhancement Silver Spectrum analysis Substrates Surface analysis (chemical) Surface chemistry |
| title | Concurrent surface enhanced infrared and Raman spectroscopy with single molecule sensitivity |
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