Trans Ligand Determines the Stability of Paramagnetic Manganese(II) Hydrides of the Type trans-[MnH(L)(dmpe)2]+ Where L is PMe3, C2H4, or CO

Paramagnetic metal hydride (PMH) complexes play important roles in catalytic applications and bioinorganic chemistry. 3d PMH chemistry has largely focused on Ti, Mn, Fe, and Co. Various MnII PMHs have been proposed as intermediates in catalysis, but isolated MnII PMHs are limited to dimeric high-spi...

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Veröffentlicht in:	Inorganic chemistry 2023-05, Vol.62 (21), p.8123-8135
Hauptverfasser:	Rennie, Benjamin E., Price, Jeffrey S., Emslie, David J. H., Morris, Robert H.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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