A voltammetric study of α- and β-hydroxides over nickel alloys

The hydrogen evolution reaction (HER) is one of the most studied electrochemical process due to the alternative energy conversion and the importance in some chemical process. The search for new electrocatalytic materials lead to investigate metals and alloys with particular characteristics/propertie...

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Veröffentlicht in:Electrochimica acta 2002-05, Vol.47 (12), p.1997-2004
Hauptverfasser: Salgado, J.R.C, Andrade, M.H.S, Silva, J.C.P, Tonholo, J
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container_end_page 2004
container_issue 12
container_start_page 1997
container_title Electrochimica acta
container_volume 47
creator Salgado, J.R.C
Andrade, M.H.S
Silva, J.C.P
Tonholo, J
description The hydrogen evolution reaction (HER) is one of the most studied electrochemical process due to the alternative energy conversion and the importance in some chemical process. The search for new electrocatalytic materials lead to investigate metals and alloys with particular characteristics/properties. This paper describes aspects of hydrogen adsorption and Ni-hydroxide formation over nickel alloys (SAF2205, INCONEL625 and MONEL400) utilizing cyclic voltammetry. The SAF2205 (6.4% Ni) alloy present behavior analogue to pure Ni electrodes to hydroxide species, and can bring some advantages to HER compared with the carbon steel (SAE1020) electrode commonly utilized in industrial process.
doi_str_mv 10.1016/S0013-4686(02)00104-4
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1873-3859
language eng
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source Elsevier ScienceDirect Journals
subjects Chemistry
Electrochemistry
Electrodes: preparations and properties
Exact sciences and technology
General and physical chemistry
HER mechanism
Hydrogen evolution
Nickel (II) hydroxide
Nickel alloys
Nickel hydride
Other electrodes
title A voltammetric study of α- and β-hydroxides over nickel alloys
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