Palladium‐Catalyzed Asymmetric Hydrogenolysis of Aryl Triflates for Construction of Axially Chiral Biaryls

Here we report the first palladium‐catalyzed asymmetric hydrogenolysis of readily available aryl triflates via desymmetrization and kinetic resolution for facile construction of axially chiral biaryl scaffolds with excellent enantioselectivities and s selectivity factors. The axially chiral monophos...

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Veröffentlicht in:	Angewandte Chemie International Edition 2023-04, Vol.62 (16), p.e202301337-n/a
Hauptverfasser:	Li, Xiang, Wang, Gao‐Wei, Liu, Li‐Xia, Yu, Chang‐Bin, Zhou, Yong‐Gui
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkylation Aromatic compounds Aryl Triflates Asymmetric Hydrogenolysis Asymmetry Axially Chiral Biaryls Desymmetrization Hydrogenolysis Palladium
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