A thermodynamic explanation for the martensitic transformation of nanometer-sized γ-iron particles embedded in a copper matrix

The martensitic transformation of nanometer-sized particles precipitating in a copper matrix is analyzed from a thermodynamic viewpoint. It is shown that there exists a critical austenitic particle size below which the austenitic phase becomes more stable than the martensitic phase and the martensit...

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Veröffentlicht in:Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 2002-10, Vol.336 (1), p.270-273
Hauptverfasser: Qin, W., Du, Y.W., Zhuang, Y.H., Chen, Z.H.
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Du, Y.W.
Zhuang, Y.H.
Chen, Z.H.
description The martensitic transformation of nanometer-sized particles precipitating in a copper matrix is analyzed from a thermodynamic viewpoint. It is shown that there exists a critical austenitic particle size below which the austenitic phase becomes more stable than the martensitic phase and the martensitic transformation cannot take place. Prolonged annealing, extraction of particle from the matrix, and plastic deformation would make the austenitic particle size exceed this critical value, and thus, cause the austenitic particles to transform to martensite. The theoretical results can interpret experimental observations well.
doi_str_mv 10.1016/S0921-5093(01)01989-X
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subjects Condensed matter: structure, mechanical and thermal properties
Equations of state, phase equilibria, and phase transitions
Exact sciences and technology
Martensitic transformation
Nanometer-sized particle
Physics
Plastic deformation
Specific phase transitions
Structural transitions in nanoscale materials
title A thermodynamic explanation for the martensitic transformation of nanometer-sized γ-iron particles embedded in a copper matrix
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