Thermal treatment of soils contaminated with gas oil: influence of soil composition and treatment temperature

Samples of two soils containing different organic matter contents, neat or contaminated with gas oil (diesel fuel oil) at 2.5 wt.% were heated from room temperature to different final temperatures (200–900 °C). The experiments, performed in an anaerobic media, simulate conditions pertinent to ex sit...

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Veröffentlicht in:Journal of hazardous materials 2002-10, Vol.94 (3), p.273-290
Hauptverfasser: Piña, Juliana, Merino, Jerónimo, Errazu, Alberto F, Bucalá, Verónica
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container_issue 3
container_start_page 273
container_title Journal of hazardous materials
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creator Piña, Juliana
Merino, Jerónimo
Errazu, Alberto F
Bucalá, Verónica
description Samples of two soils containing different organic matter contents, neat or contaminated with gas oil (diesel fuel oil) at 2.5 wt.% were heated from room temperature to different final temperatures (200–900 °C). The experiments, performed in an anaerobic media, simulate conditions pertinent to ex situ thermal desorptive and thermal destructive treatments. The products generated during the heating were collected and light gases were analyzed by gas chromatography. The results indicate that the chemical composition of the soil is a key factor since it strongly influences the quantity and composition of the off-gases. According to the liquid and light gas yields, the gas oil does not affect appreciably the generation of pyrolysis products of the own soil constituents and the gas oil does not suffer significant chemical transformations even at high operating temperatures (e.g. 900 °C). With surface areas of 16 000 cm 2/g (Soil A) and 85 000 cm 2/g (Soil B) based on the monolayer adsorbed model, 4 and 20%, respectively, of the original gas oil can be adsorbed. These values are in good agreement with experimental data. Even for high temperatures, the employed thermal treatment is capable to practically remove the gas oil from the soil bed without changing appreciably the original chemical composition of the contaminant.
doi_str_mv 10.1016/S0304-3894(02)00081-X
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subjects Anaerobic treatment
Applied sciences
Carcinogens, Environmental - analysis
Chemical composition
Contaminants
Contamination
Decontamination. Miscellaneous
Diesel fuels
Earth sciences
Earth, ocean, space
Engineering and environment geology. Geothermics
Environmental Pollution - prevention & control
Exact sciences and technology
Gas oil contamination
Gasoline - analysis
Mathematical models
Natural gas
Pollution
Pollution, environment geology
Soil
Soil (material)
Soil and sediments pollution
Soil cleanup
Soil Pollutants - analysis
Soil remediation
Soils
Temperature
Thermal desorption
Thermal destruction
thermal treatment
Volatilization
title Thermal treatment of soils contaminated with gas oil: influence of soil composition and treatment temperature
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