Synthesis and properties of polystyrene/graphite nanocomposites
In this paper, graphite/polystyrene nanocomposite is synthesized by in situ polymerization of styrene in a tetrahydrofuran (THF) solution system of potassium (K)--THF--graphite intercalation compound (GIC). K--THF--GIC has proved to initiate polymerization of styrene by the anionic mechanism. Due to...
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Veröffentlicht in: | Polymer (Guilford) 2002-04, Vol.43 (8), p.2245-2248 |
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creator | Xiao, Min Sun, Luyi Liu, Jingjing Li, Yun Gong, Kecheng |
description | In this paper, graphite/polystyrene nanocomposite is synthesized by in situ polymerization of styrene in a tetrahydrofuran (THF) solution system of potassium (K)--THF--graphite intercalation compound (GIC). K--THF--GIC has proved to initiate polymerization of styrene by the anionic mechanism. Due to the interfacial interaction between the graphite nanolayers and the polymer, the composites exhibit higher glass transition temperature and higher thermal stability when compared to polystyrene. The percolation threshold in the conductivity of the composites is lesser than 8.2 wt% and the dielectric constant can reach as high as 136. |
doi_str_mv | 10.1016/S0032-3861(02)00022-8 |
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K--THF--GIC has proved to initiate polymerization of styrene by the anionic mechanism. Due to the interfacial interaction between the graphite nanolayers and the polymer, the composites exhibit higher glass transition temperature and higher thermal stability when compared to polystyrene. The percolation threshold in the conductivity of the composites is lesser than 8.2 wt% and the dielectric constant can reach as high as 136.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/S0032-3861(02)00022-8</identifier><identifier>CODEN: POLMAG</identifier><language>eng</language><publisher>Oxford: Elsevier</publisher><subject>Applied sciences ; Composites ; Exact sciences and technology ; Forms of application and semi-finished materials ; Polymer industry, paints, wood ; Technology of polymers</subject><ispartof>Polymer (Guilford), 2002-04, Vol.43 (8), p.2245-2248</ispartof><rights>2002 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c498t-3101a4a0aced6250757e06e1515cf0cc23a8070b403145ecbd1f0f58e6dc022d3</citedby><cites>FETCH-LOGICAL-c498t-3101a4a0aced6250757e06e1515cf0cc23a8070b403145ecbd1f0f58e6dc022d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=13465368$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Xiao, Min</creatorcontrib><creatorcontrib>Sun, Luyi</creatorcontrib><creatorcontrib>Liu, Jingjing</creatorcontrib><creatorcontrib>Li, Yun</creatorcontrib><creatorcontrib>Gong, Kecheng</creatorcontrib><title>Synthesis and properties of polystyrene/graphite nanocomposites</title><title>Polymer (Guilford)</title><description>In this paper, graphite/polystyrene nanocomposite is synthesized by in situ polymerization of styrene in a tetrahydrofuran (THF) solution system of potassium (K)--THF--graphite intercalation compound (GIC). K--THF--GIC has proved to initiate polymerization of styrene by the anionic mechanism. Due to the interfacial interaction between the graphite nanolayers and the polymer, the composites exhibit higher glass transition temperature and higher thermal stability when compared to polystyrene. The percolation threshold in the conductivity of the composites is lesser than 8.2 wt% and the dielectric constant can reach as high as 136.</description><subject>Applied sciences</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNqNkEtPwzAQhC0EEqXwE5ByAcEhdG3HjntCqOIlVeJQOFuus6FBaRy86SH_nvQhuHJarfTtzOwwdsnhjgPXkwWAFKk0mt-AuAUAIVJzxEbc5DIVYsqP2egXOWVnRF9bSIlsxO4XfdOtkCpKXFMkbQwtxq5CSkKZtKHuqesjNjj5jK5dVR0mjWuCD-s20LDROTspXU14cZhj9vH0-D57Sedvz6-zh3nqs6npUjkEdZkD57HQQkGucgSNXHHlS_BeSGcgh2UGkmcK_bLgJZTKoC788E4hx-x6rzsk_N4gdXZdkce6dg2GDVmR59k01-Y_oFRSwwCqPehjIIpY2jZWaxd7y8Fue7W7Xu22NAvC7nq1W4Org4Ej7-oyusZX9HcsMz3oG_kDk0Z4dg</recordid><startdate>20020401</startdate><enddate>20020401</enddate><creator>Xiao, Min</creator><creator>Sun, Luyi</creator><creator>Liu, Jingjing</creator><creator>Li, Yun</creator><creator>Gong, Kecheng</creator><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>F28</scope><scope>FR3</scope></search><sort><creationdate>20020401</creationdate><title>Synthesis and properties of polystyrene/graphite nanocomposites</title><author>Xiao, Min ; Sun, Luyi ; Liu, Jingjing ; Li, Yun ; Gong, Kecheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c498t-3101a4a0aced6250757e06e1515cf0cc23a8070b403145ecbd1f0f58e6dc022d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Applied sciences</topic><topic>Composites</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xiao, Min</creatorcontrib><creatorcontrib>Sun, Luyi</creatorcontrib><creatorcontrib>Liu, Jingjing</creatorcontrib><creatorcontrib>Li, Yun</creatorcontrib><creatorcontrib>Gong, Kecheng</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xiao, Min</au><au>Sun, Luyi</au><au>Liu, Jingjing</au><au>Li, Yun</au><au>Gong, Kecheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and properties of polystyrene/graphite nanocomposites</atitle><jtitle>Polymer (Guilford)</jtitle><date>2002-04-01</date><risdate>2002</risdate><volume>43</volume><issue>8</issue><spage>2245</spage><epage>2248</epage><pages>2245-2248</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>In this paper, graphite/polystyrene nanocomposite is synthesized by in situ polymerization of styrene in a tetrahydrofuran (THF) solution system of potassium (K)--THF--graphite intercalation compound (GIC). 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subjects | Applied sciences Composites Exact sciences and technology Forms of application and semi-finished materials Polymer industry, paints, wood Technology of polymers |
title | Synthesis and properties of polystyrene/graphite nanocomposites |
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