A Fourfold Gold(I)−Aryl Macrocycle with Hyperbolic Geometry and its Reductive Elimination to a Carbon Nanoring Host

An ethylene glycol‐decorated [6]cyclo‐meta‐phenylene (CMP) macrocycle was synthesized and utilized as a subunit to construct a fourfold AuI2−aryl metallacycle with an overall square arrangement. The corners consist of rigid dinuclear gold(I) complexes previously known to form only triangular metalla...

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Veröffentlicht in:	Angewandte Chemie International Edition 2023-04, Vol.62 (16), p.e202217917-n/a
Hauptverfasser:	Grabicki, Niklas, Fisher, Sergey, Dumele, Oliver
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Carbon Cycloparaphenylenes Ethylene glycol Gold Host–Guest Systems Macrocycles Molecular Recognition NMR Nuclear magnetic resonance Organometallic compounds Supramolecular Chemistry
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