Computational Study of Mechanisms and Tether Length Effects of Rh‐Catalyzed [3+2] and [3+2+1] Reactions of Ene/Yne‐Vinylcyclopropanes

DFT calculations have been applied to study the mechanisms of [3+2] and [3+2+1] reactions of ene/yne‐vinylcyclopropanes (shorted as ene/yne‐VCPs). The [3+2] reactions of ene/yne‐VCPs start from C−C cleavage of cyclopropane (CP cleavage) to form six‐membered rhodacycle, followed by alkene/alkyne inse...

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Veröffentlicht in:	Chemistry, an Asian journal an Asian journal, 2023-04, Vol.18 (7), p.e202300032-n/a
Hauptverfasser:	Zhang, Guan‐Yu, Lin, Mu, Yu, Zhi‐Xiang
Format:	Artikel
Sprache:	eng
Schlagworte:	3+2 3+2+1 alkene/alkyne insertion Alkynes Carbon monoxide Chemical reactions Chemistry Cleavage Cycloaddition Reactions Cyclopropane Insertion Rhodium Catalysis Substrates tether length effect Tethers
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