Sol-gel derived hydroxyapatite coatings on titanium substrate

Biomaterials, in particular those used for orthopaedic prostheses, consist of a metallic substrate, exhibiting excellent mechanical properties, coated with a ceramic layer, which guarantees resistance to the corrosion and an elevated bioactivity. In this paper the preparation of sol-gel films of hyd...

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Veröffentlicht in:Journal of materials science 2000-06, Vol.35 (11), p.2791-2797
Hauptverfasser: Montenero, A, Gnappi, G, Ferrari, F, Cesari, M, Salvioli, E, Mattogno, L, Kaciulis, S, Fini, M
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container_end_page 2797
container_issue 11
container_start_page 2791
container_title Journal of materials science
container_volume 35
creator Montenero, A
Gnappi, G
Ferrari, F
Cesari, M
Salvioli, E
Mattogno, L
Kaciulis, S
Fini, M
description Biomaterials, in particular those used for orthopaedic prostheses, consist of a metallic substrate, exhibiting excellent mechanical properties, coated with a ceramic layer, which guarantees resistance to the corrosion and an elevated bioactivity. In this paper the preparation of sol-gel films of hydroxyapatite, HA (Ca10(PO4)6(OH)2), on titanium substrate is described. The samples were obtained through the dip-coating method, starting from a colloidal suspension of hydroxyapatite. In order to increase the adhesion between the HA film and the metallic substrate, the same substrate has been preliminarily coated either with titanium oxide, TiO2 (in the anatase or rutile phase), or calcium titanate, CaTiO3 (perovskite). Also these latter films have been deposited from a sol-gel solution. The characterization of the films through XRD, SEM, and AFM gave good results for the crystallinity of the deposited HA; for what concerns the sample morphology, the films turned out to be homogeneous and crack-free.
doi_str_mv 10.1023/A:1004738900778
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subjects Anatase
Biocompatibility
Biomedical materials
Calcium titanate
Ceramic coatings
Corrosion resistance
Dip coatings
Hydroxyapatite
Immersion coating
Materials science
Mechanical properties
Morphology
Perovskites
Prostheses
Protective coatings
Sol-gel processes
Substrates
Surgical implants
Titanium
Titanium dioxide
Titanium oxides
title Sol-gel derived hydroxyapatite coatings on titanium substrate
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