Structure of Polymorphous Modifications of Double Sodium and Indium Phosphate
Polymorphous modifications of β- and α-Na3In(PO4)2 were synthesized and found to be related to the β-K2SO4 structure type. They crystallize in a monoclinic system (space groups P21/c and P21/m, respectively), with unit cell parameters a=7.127(1) Å, b=18.220(1) Å, c=8.616(1) Å, β=143.36(1)° for β-Na3...
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| Veröffentlicht in: | Journal of solid state chemistry 2000-01, Vol.149 (1), p.99-106 |
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| container_title | Journal of solid state chemistry |
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| creator | Zhizhin, M.G. Morozov, V.A. Bobylev, A.P. Popov, A.M. Spiridonov, F.M. Komissarova, L.N. Lazoryak, B.I. |
| description | Polymorphous modifications of β- and α-Na3In(PO4)2 were synthesized and found to be related to the β-K2SO4 structure type. They crystallize in a monoclinic system (space groups P21/c and P21/m, respectively), with unit cell parameters a=7.127(1) Å, b=18.220(1) Å, c=8.616(1) Å, β=143.36(1)° for β-Na3In(PO4)2; and a=8.6335(1) Å, b=5.4550(1) Å, c=7.0482(1) Å, β=90.295(1)° for α-Na3In(PO4)2. Their crystal structures were determined by Rietveld analysis [Rwp=7.72, RI=3.02 (β-); Rwp=6.59, RI=3.06 (α-)]. Indium cations occupy the X position while sodium cations occupy the X and Y positions of the β-K2SO4-type structure. The PO3−4 tetrahedron rotation leads to a decrease in the coordination number of the Y position. |
| doi_str_mv | 10.1006/jssc.1999.8501 |
| format | Article |
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They crystallize in a monoclinic system (space groups P21/c and P21/m, respectively), with unit cell parameters a=7.127(1) Å, b=18.220(1) Å, c=8.616(1) Å, β=143.36(1)° for β-Na3In(PO4)2; and a=8.6335(1) Å, b=5.4550(1) Å, c=7.0482(1) Å, β=90.295(1)° for α-Na3In(PO4)2. Their crystal structures were determined by Rietveld analysis [Rwp=7.72, RI=3.02 (β-); Rwp=6.59, RI=3.06 (α-)]. Indium cations occupy the X position while sodium cations occupy the X and Y positions of the β-K2SO4-type structure. The PO3−4 tetrahedron rotation leads to a decrease in the coordination number of the Y position.</description><identifier>ISSN: 0022-4596</identifier><identifier>EISSN: 1095-726X</identifier><identifier>DOI: 10.1006/jssc.1999.8501</identifier><language>eng</language><publisher>Elsevier Inc</publisher><subject>indium ; infrared spectroscopy ; phosphates ; Rietveld ; sodium ; X-ray diffraction</subject><ispartof>Journal of solid state chemistry, 2000-01, Vol.149 (1), p.99-106</ispartof><rights>2000 Academic Press</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c383t-67f1a1fd4c282668eb0d105b5a239830dea9de08789109a565d47b151f06e813</citedby><cites>FETCH-LOGICAL-c383t-67f1a1fd4c282668eb0d105b5a239830dea9de08789109a565d47b151f06e813</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1006/jssc.1999.8501$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27923,27924,45994</link.rule.ids></links><search><creatorcontrib>Zhizhin, M.G.</creatorcontrib><creatorcontrib>Morozov, V.A.</creatorcontrib><creatorcontrib>Bobylev, A.P.</creatorcontrib><creatorcontrib>Popov, A.M.</creatorcontrib><creatorcontrib>Spiridonov, F.M.</creatorcontrib><creatorcontrib>Komissarova, L.N.</creatorcontrib><creatorcontrib>Lazoryak, B.I.</creatorcontrib><title>Structure of Polymorphous Modifications of Double Sodium and Indium Phosphate</title><title>Journal of solid state chemistry</title><description>Polymorphous modifications of β- and α-Na3In(PO4)2 were synthesized and found to be related to the β-K2SO4 structure type. They crystallize in a monoclinic system (space groups P21/c and P21/m, respectively), with unit cell parameters a=7.127(1) Å, b=18.220(1) Å, c=8.616(1) Å, β=143.36(1)° for β-Na3In(PO4)2; and a=8.6335(1) Å, b=5.4550(1) Å, c=7.0482(1) Å, β=90.295(1)° for α-Na3In(PO4)2. Their crystal structures were determined by Rietveld analysis [Rwp=7.72, RI=3.02 (β-); Rwp=6.59, RI=3.06 (α-)]. Indium cations occupy the X position while sodium cations occupy the X and Y positions of the β-K2SO4-type structure. The PO3−4 tetrahedron rotation leads to a decrease in the coordination number of the Y position.</description><subject>indium</subject><subject>infrared spectroscopy</subject><subject>phosphates</subject><subject>Rietveld</subject><subject>sodium</subject><subject>X-ray diffraction</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNp1kL1PwzAQxS0EEqWwMmdiSzgnseOMqHxVakWldmCzHPuiukriYidI_e9JKCvTne7eO737EXJPIaEA_PEQgk5oWZaJYEAvyIxCyeIi5Z-XZAaQpnHOSn5NbkI4AFDKRD4j623vB90PHiNXRxvXnFrnj3s3hGjtjK2tVr11XZi2z26oGoy243xoI9WZaNn9tpu9C8e96vGWXNWqCXj3V-dk9_qyW7zHq4-35eJpFetMZH3Mi5oqWptcpyLlXGAFhgKrmEqzUmRgUJUGQRSiHH9QjDOTFxVltAaOgmZz8nA-e_Tua8DQy9YGjU2jOhyTy7QoshxyNgqTs1B7F4LHWh69bZU_SQpygiYnaHKCJidoo0GcDTim_7boZdAWO43GetS9NM7-Z_0BeC5zsA</recordid><startdate>200001</startdate><enddate>200001</enddate><creator>Zhizhin, M.G.</creator><creator>Morozov, V.A.</creator><creator>Bobylev, A.P.</creator><creator>Popov, A.M.</creator><creator>Spiridonov, F.M.</creator><creator>Komissarova, L.N.</creator><creator>Lazoryak, B.I.</creator><general>Elsevier Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>200001</creationdate><title>Structure of Polymorphous Modifications of Double Sodium and Indium Phosphate</title><author>Zhizhin, M.G. ; Morozov, V.A. ; Bobylev, A.P. ; Popov, A.M. ; Spiridonov, F.M. ; Komissarova, L.N. ; Lazoryak, B.I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c383t-67f1a1fd4c282668eb0d105b5a239830dea9de08789109a565d47b151f06e813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>indium</topic><topic>infrared spectroscopy</topic><topic>phosphates</topic><topic>Rietveld</topic><topic>sodium</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhizhin, M.G.</creatorcontrib><creatorcontrib>Morozov, V.A.</creatorcontrib><creatorcontrib>Bobylev, A.P.</creatorcontrib><creatorcontrib>Popov, A.M.</creatorcontrib><creatorcontrib>Spiridonov, F.M.</creatorcontrib><creatorcontrib>Komissarova, L.N.</creatorcontrib><creatorcontrib>Lazoryak, B.I.</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhizhin, M.G.</au><au>Morozov, V.A.</au><au>Bobylev, A.P.</au><au>Popov, A.M.</au><au>Spiridonov, F.M.</au><au>Komissarova, L.N.</au><au>Lazoryak, B.I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure of Polymorphous Modifications of Double Sodium and Indium Phosphate</atitle><jtitle>Journal of solid state chemistry</jtitle><date>2000-01</date><risdate>2000</risdate><volume>149</volume><issue>1</issue><spage>99</spage><epage>106</epage><pages>99-106</pages><issn>0022-4596</issn><eissn>1095-726X</eissn><abstract>Polymorphous modifications of β- and α-Na3In(PO4)2 were synthesized and found to be related to the β-K2SO4 structure type. They crystallize in a monoclinic system (space groups P21/c and P21/m, respectively), with unit cell parameters a=7.127(1) Å, b=18.220(1) Å, c=8.616(1) Å, β=143.36(1)° for β-Na3In(PO4)2; and a=8.6335(1) Å, b=5.4550(1) Å, c=7.0482(1) Å, β=90.295(1)° for α-Na3In(PO4)2. Their crystal structures were determined by Rietveld analysis [Rwp=7.72, RI=3.02 (β-); Rwp=6.59, RI=3.06 (α-)]. Indium cations occupy the X position while sodium cations occupy the X and Y positions of the β-K2SO4-type structure. The PO3−4 tetrahedron rotation leads to a decrease in the coordination number of the Y position.</abstract><pub>Elsevier Inc</pub><doi>10.1006/jssc.1999.8501</doi><tpages>8</tpages></addata></record> |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | indium infrared spectroscopy phosphates Rietveld sodium X-ray diffraction |
| title | Structure of Polymorphous Modifications of Double Sodium and Indium Phosphate |
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