Structural stability of aluminum stabilized alpha nickel hydroxide as a positive electrode material for alkaline secondary batteries
Nanostructured, aluminum-stabilized nickel, hydroxides described as Ni 1− x Al x (OH) 2.(CO 3) x/2 · nH 2O ( x=0.05–0.2), which are similar to α-Ni(OH) 2· xH 2O in crystal structure are examined as cathode materials for Ni–Cd cells. The structure, morphology and electrochemical performance are inves...
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Veröffentlicht in: | Journal of power sources 2000, Vol.89 (1), p.40-45 |
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creator | Dai, Jinxiang Li, Sam F.Y Xiao, T.Danny Wang, Donald M Reisner, David E |
description | Nanostructured, aluminum-stabilized nickel, hydroxides described as Ni
1−
x
Al
x
(OH)
2.(CO
3)
x/2
·
nH
2O (
x=0.05–0.2), which are similar to α-Ni(OH)
2·
xH
2O in crystal structure are examined as cathode materials for Ni–Cd cells. The structure, morphology and electrochemical performance are investigated. The structural changes and stability of nanophase aluminum-stabilized, alpha nickel hydroxides with different
x values analyzed during cycling by means of powder X-ray diffraction. Compared with β-Ni(OH)
2, the nanophase, aluminum-stabilized α-Ni(OH)
2 with
x=0.15 is highly stable against overcharge. |
doi_str_mv | 10.1016/S0378-7753(00)00391-8 |
format | Article |
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1−
x
Al
x
(OH)
2.(CO
3)
x/2
·
nH
2O (
x=0.05–0.2), which are similar to α-Ni(OH)
2·
xH
2O in crystal structure are examined as cathode materials for Ni–Cd cells. The structure, morphology and electrochemical performance are investigated. The structural changes and stability of nanophase aluminum-stabilized, alpha nickel hydroxides with different
x values analyzed during cycling by means of powder X-ray diffraction. Compared with β-Ni(OH)
2, the nanophase, aluminum-stabilized α-Ni(OH)
2 with
x=0.15 is highly stable against overcharge.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/S0378-7753(00)00391-8</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Alpha nickel hydroxide ; Applied sciences ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Exact sciences and technology ; Secondary battery</subject><ispartof>Journal of power sources, 2000, Vol.89 (1), p.40-45</ispartof><rights>2000 Elsevier Science S.A.</rights><rights>2000 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c474t-4866f7023b6dff65a469e58d484bfafd0fcbe26a44ec254cd0c0c4892488073f3</citedby><cites>FETCH-LOGICAL-c474t-4866f7023b6dff65a469e58d484bfafd0fcbe26a44ec254cd0c0c4892488073f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0378-7753(00)00391-8$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,782,786,3554,4028,27932,27933,27934,46004</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1413200$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Dai, Jinxiang</creatorcontrib><creatorcontrib>Li, Sam F.Y</creatorcontrib><creatorcontrib>Xiao, T.Danny</creatorcontrib><creatorcontrib>Wang, Donald M</creatorcontrib><creatorcontrib>Reisner, David E</creatorcontrib><title>Structural stability of aluminum stabilized alpha nickel hydroxide as a positive electrode material for alkaline secondary batteries</title><title>Journal of power sources</title><description>Nanostructured, aluminum-stabilized nickel, hydroxides described as Ni
1−
x
Al
x
(OH)
2.(CO
3)
x/2
·
nH
2O (
x=0.05–0.2), which are similar to α-Ni(OH)
2·
xH
2O in crystal structure are examined as cathode materials for Ni–Cd cells. The structure, morphology and electrochemical performance are investigated. The structural changes and stability of nanophase aluminum-stabilized, alpha nickel hydroxides with different
x values analyzed during cycling by means of powder X-ray diffraction. Compared with β-Ni(OH)
2, the nanophase, aluminum-stabilized α-Ni(OH)
2 with
x=0.15 is highly stable against overcharge.</description><subject>Alpha nickel hydroxide</subject><subject>Applied sciences</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Exact sciences and technology</subject><subject>Secondary battery</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNqFkMGKFDEQhoMoOI4-gpCDiB5aK510J3MSWdxVWPCweg7ppMLGTXfGJL04nn1wMzurHj0Ffr6_KvUR8pzBGwZsfHsFXKpOyoG_AngNwHesUw_IhinJu14Ow0Oy-Ys8Jk9K-QYAjEnYkF9XNa-2rtlEWqqZQgz1QJOnJq5zWNb5T_oTXcv214Yuwd5gpNcHl9OP4JCaQg3dpxJquEWKEW3NqeWzqZhDG-xTbt0bE8OCtKBNizP5QCdTjwCWp-SRN7Hgs_t3S76ef_hy9rG7_Hzx6ez9ZWeFFLUTahy9hJ5Po_N-HIwYdzgoJ5SYvPEOvJ2wH40QaPtBWAcWrFC7XigFknu-JS9Pc_c5fV-xVD2HYjFGs2Bai-6l5JwL1cDhBNqcSsno9T6Huf1ZM9BH5_rOuT4K1QD6zrk-9l7cLzDFmuizWWwo_8qC8b6xW_LuhGE79jZg1sUGXCy6kJs87VL4z6LfB7yZXQ</recordid><startdate>2000</startdate><enddate>2000</enddate><creator>Dai, Jinxiang</creator><creator>Li, Sam F.Y</creator><creator>Xiao, T.Danny</creator><creator>Wang, Donald M</creator><creator>Reisner, David E</creator><general>Elsevier B.V</general><general>Elsevier Sequoia</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>2000</creationdate><title>Structural stability of aluminum stabilized alpha nickel hydroxide as a positive electrode material for alkaline secondary batteries</title><author>Dai, Jinxiang ; Li, Sam F.Y ; Xiao, T.Danny ; Wang, Donald M ; Reisner, David E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c474t-4866f7023b6dff65a469e58d484bfafd0fcbe26a44ec254cd0c0c4892488073f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>Alpha nickel hydroxide</topic><topic>Applied sciences</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Exact sciences and technology</topic><topic>Secondary battery</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dai, Jinxiang</creatorcontrib><creatorcontrib>Li, Sam F.Y</creatorcontrib><creatorcontrib>Xiao, T.Danny</creatorcontrib><creatorcontrib>Wang, Donald M</creatorcontrib><creatorcontrib>Reisner, David E</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dai, Jinxiang</au><au>Li, Sam F.Y</au><au>Xiao, T.Danny</au><au>Wang, Donald M</au><au>Reisner, David E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural stability of aluminum stabilized alpha nickel hydroxide as a positive electrode material for alkaline secondary batteries</atitle><jtitle>Journal of power sources</jtitle><date>2000</date><risdate>2000</risdate><volume>89</volume><issue>1</issue><spage>40</spage><epage>45</epage><pages>40-45</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><coden>JPSODZ</coden><abstract>Nanostructured, aluminum-stabilized nickel, hydroxides described as Ni
1−
x
Al
x
(OH)
2.(CO
3)
x/2
·
nH
2O (
x=0.05–0.2), which are similar to α-Ni(OH)
2·
xH
2O in crystal structure are examined as cathode materials for Ni–Cd cells. The structure, morphology and electrochemical performance are investigated. The structural changes and stability of nanophase aluminum-stabilized, alpha nickel hydroxides with different
x values analyzed during cycling by means of powder X-ray diffraction. Compared with β-Ni(OH)
2, the nanophase, aluminum-stabilized α-Ni(OH)
2 with
x=0.15 is highly stable against overcharge.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/S0378-7753(00)00391-8</doi><tpages>6</tpages></addata></record> |
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issn | 0378-7753 1873-2755 |
language | eng |
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source | Access via ScienceDirect (Elsevier) |
subjects | Alpha nickel hydroxide Applied sciences Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology Secondary battery |
title | Structural stability of aluminum stabilized alpha nickel hydroxide as a positive electrode material for alkaline secondary batteries |
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