Structural stability of aluminum stabilized alpha nickel hydroxide as a positive electrode material for alkaline secondary batteries

Nanostructured, aluminum-stabilized nickel, hydroxides described as Ni 1− x Al x (OH) 2.(CO 3) x/2 · nH 2O ( x=0.05–0.2), which are similar to α-Ni(OH) 2· xH 2O in crystal structure are examined as cathode materials for Ni–Cd cells. The structure, morphology and electrochemical performance are inves...

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Veröffentlicht in:Journal of power sources 2000, Vol.89 (1), p.40-45
Hauptverfasser: Dai, Jinxiang, Li, Sam F.Y, Xiao, T.Danny, Wang, Donald M, Reisner, David E
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container_issue 1
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container_title Journal of power sources
container_volume 89
creator Dai, Jinxiang
Li, Sam F.Y
Xiao, T.Danny
Wang, Donald M
Reisner, David E
description Nanostructured, aluminum-stabilized nickel, hydroxides described as Ni 1− x Al x (OH) 2.(CO 3) x/2 · nH 2O ( x=0.05–0.2), which are similar to α-Ni(OH) 2· xH 2O in crystal structure are examined as cathode materials for Ni–Cd cells. The structure, morphology and electrochemical performance are investigated. The structural changes and stability of nanophase aluminum-stabilized, alpha nickel hydroxides with different x values analyzed during cycling by means of powder X-ray diffraction. Compared with β-Ni(OH) 2, the nanophase, aluminum-stabilized α-Ni(OH) 2 with x=0.15 is highly stable against overcharge.
doi_str_mv 10.1016/S0378-7753(00)00391-8
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subjects Alpha nickel hydroxide
Applied sciences
Direct energy conversion and energy accumulation
Electrical engineering. Electrical power engineering
Electrical power engineering
Electrochemical conversion: primary and secondary batteries, fuel cells
Exact sciences and technology
Secondary battery
title Structural stability of aluminum stabilized alpha nickel hydroxide as a positive electrode material for alkaline secondary batteries
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