Copper(I) Photocatalyzed Bromonitroalkylation of Olefins: Evidence for Highly Efficient Inner‐Sphere Pathways

We report the visible light‐mediated copper‐catalyzed vicinal difunctionalization of olefins utilizing bromonitroalkanes as ATRA reagents. This protocol is characterized by high yields and fast reaction times under environmentally benign reaction conditions with exceptional scope, allowing the rapid...

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Veröffentlicht in:	Angewandte Chemie International Edition 2023-04, Vol.62 (16), p.e202219086-n/a
Hauptverfasser:	Reichle, Alexander, Koch, Magdalena, Sterzel, Hannes, Großkopf, Lea‐Joy, Floss, Johannes, Rehbein, Julia, Reiser, Oliver
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Biological activity Catalysis Copper Homogeneous Catalysis Intermediates Iridium Photocatalysis Photoredox catalysis Radicals Reaction Mechanism Reagents
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