Combustion‐Assisted Polyol Reduction Method to Prepare Highly Transparent and Efficient Pt Counter Electrodes for Bifacial Dye‐Sensitized Solar Cells

A combustion‐assisted polyol reduction (CPR) method has been developed to deposit electrocatalytically efficient and transparent Pt counter electrodes (CEs) for bifacial dye‐sensitized solar cells (DSSCs). Compared with conventional thermal decomposition of Pt precursors, CPR allows for a decrease in reduction temperature to 150 °C. The low‐temperature processing is attributed to adding an organic fuel, acetylacetone (Hacac), which provides extra heat to lower reduction energy. In addition, the stable Pt complexes can simultaneously be formed in ethylene glycol (EG) and Hacac system, which leads to Pt nanoparticle size regulation. A ratio of Hacac to EG is optimized to achieve excellent electrocatalytic activity and high visible light transmittance for CEs. The bifacial DSSCs fabricated with CPR‐Pt CEs (EG : Hacac=1 : 16) reach efficiencies of 6.71±0.16% and 6.41±0.15% in front and back irradiations, respectively. Combustion‐assisted polyol reduction allows for achieving optically transparent and electrocatalytically efficient Pt counter electrodes (CEs) for bifacial dye‐sensitized solar cells (DSSCs). The best bifacial DSSCs exhibit power conversion efficiencies of 6.71% and 6.41% in front and back irradiations, respectively.