Synthesis of Phosphine-Functionalized Silicon Cubane and Its Oxidative Addition, Giving a Bis(silyl)copper Complex
A new strategy for the introduction of a second type of Si atom to silicon cubanes has been developed starting from the tricyclic hexasilane dianion [Ar6Si6]2– (Ar = 2,4,6-Me3C6H2). Treatment of the dianion with Ar′SiCl3, followed by KC8, gave new types of octasilacubanes Ar6Ar′2Si8 [Ar′ = 2,4,6-iPr...
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| Veröffentlicht in: | Inorganic chemistry 2023-02, Vol.62 (6), p.2503-2507 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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