Single-electron and two-electron transfer in the anionic polymerization of vinyl monomers and the ring-opening polymerization of lactones

Single‐electron‐transfer (SET) and two‐electron‐transfer reactions and their mechanisms were examined in the anionic polymerization of vinyl monomers and in the ring‐opening polymerization of lactones. SET resulted in the formation of radical anions or enolates at the initiation step of styrene or l...

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Veröffentlicht in:	Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2002-07, Vol.40 (13), p.2158-2165
1. Verfasser:	JEDLINSKI, Zbigniew
Format:	Artikel
Sprache:	eng
Schlagworte:	anionic polymerization Applied sciences carbanions catalysis electron transfer Exact sciences and technology lactones Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts radical anions ring-opening polymerization styrene
Online-Zugang:	Volltext
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