The additional nitrogen atom breaks the uranyl structure: a combined photoelectron spectroscopy and theoretical study of NUO2

We report a joint photoelectron spectroscopic and relativistic quantum chemistry study on gaseous NUO2−. The electron affinity (EA) of the neutral NUO2 molecule is reported for the first time with a value of 2.602(28) eV. The U–O and U–N stretching vibrational modes for the ground state and the firs...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2023-02, Vol.25 (6), p.4794-4802
Hauptverfasser:	Hong, Jing, Han, Changcai, Zejie Fei, Tang, Yuanyuan, Liu, Yancheng, Hong-Guang Xu, Wang, Mingqing, Liu, Hongtao, Xiao-Gen Xiong, Dong, Changwu
Format:	Artikel
Sprache:	eng
Schlagworte:	Angles (geometry) Anions Chemical bonds Electron affinity Ground state Mathematical analysis Nitrogen Photoelectrons Planar structures Quantum chemistry Relativistic effects Strong interactions (field theory) Vibration mode
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