Reconsideration of SEI stability: reversible lithium intercalation into graphite electrodes in trans-2,3-butylene carbonate
Lithium ion batteries with graphitic carbon anodes and LiCoO 2 cathodes are cycled reversibly in electrolytes based on trans-2,3-butylene carbonate ( t-BC), even in the absence of ethylene carbonate. While the poor interfacial film (the solid electrolyte interface (SEI)) on the lithium electrode can...
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| Veröffentlicht in: | Journal of power sources 2002-01, Vol.104 (1), p.7-12 |
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| container_title | Journal of power sources |
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| creator | Chung, Geun-Chang |
| description | Lithium ion batteries with graphitic carbon anodes and LiCoO
2 cathodes are cycled reversibly in electrolytes based on
trans-2,3-butylene carbonate (
t-BC), even in the absence of ethylene carbonate. While the poor interfacial film (the solid electrolyte interface (SEI)) on the lithium electrode can be readily explained in terms of previous models of its stability, this highly reversible behavior of graphite is hard to account for. To explain this profound difference in the SEI stability of the two electrodes, we have taken into account the influence that the nature of the electrode (lithium metal versus graphite) and the type of the reaction site (basal plane versus edge sites) exert on the solvent reduction pathways. |
| doi_str_mv | 10.1016/S0378-7753(01)00843-6 |
| format | Article |
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2 cathodes are cycled reversibly in electrolytes based on
trans-2,3-butylene carbonate (
t-BC), even in the absence of ethylene carbonate. While the poor interfacial film (the solid electrolyte interface (SEI)) on the lithium electrode can be readily explained in terms of previous models of its stability, this highly reversible behavior of graphite is hard to account for. To explain this profound difference in the SEI stability of the two electrodes, we have taken into account the influence that the nature of the electrode (lithium metal versus graphite) and the type of the reaction site (basal plane versus edge sites) exert on the solvent reduction pathways.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/S0378-7753(01)00843-6</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Applied sciences ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrolyte ; Exact sciences and technology ; Graphite ; Graphite exfoliation ; Lithium ion battery ; SEI ; Trans-butylene carbonate</subject><ispartof>Journal of power sources, 2002-01, Vol.104 (1), p.7-12</ispartof><rights>2002 Elsevier Science B.V.</rights><rights>2002 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c368t-b8c3ade252f89e1bf56e3da43e03aee24088823ce12ba8483d39ca5817215c863</citedby><cites>FETCH-LOGICAL-c368t-b8c3ade252f89e1bf56e3da43e03aee24088823ce12ba8483d39ca5817215c863</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0378-7753(01)00843-6$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=13450104$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Chung, Geun-Chang</creatorcontrib><title>Reconsideration of SEI stability: reversible lithium intercalation into graphite electrodes in trans-2,3-butylene carbonate</title><title>Journal of power sources</title><description>Lithium ion batteries with graphitic carbon anodes and LiCoO
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trans-2,3-butylene carbonate (
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trans-2,3-butylene carbonate (
t-BC), even in the absence of ethylene carbonate. While the poor interfacial film (the solid electrolyte interface (SEI)) on the lithium electrode can be readily explained in terms of previous models of its stability, this highly reversible behavior of graphite is hard to account for. To explain this profound difference in the SEI stability of the two electrodes, we have taken into account the influence that the nature of the electrode (lithium metal versus graphite) and the type of the reaction site (basal plane versus edge sites) exert on the solvent reduction pathways.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/S0378-7753(01)00843-6</doi><tpages>6</tpages></addata></record> |
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| ispartof | Journal of power sources, 2002-01, Vol.104 (1), p.7-12 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Applied sciences Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrolyte Exact sciences and technology Graphite Graphite exfoliation Lithium ion battery SEI Trans-butylene carbonate |
| title | Reconsideration of SEI stability: reversible lithium intercalation into graphite electrodes in trans-2,3-butylene carbonate |
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