First crystal structure of an Fe() anionic complex based on a pyruvic acid thiosemicarbazone ligand with Li: synthesis, features of magnetic behavior and theoretical analysis

The iron( iii ) anionic complex based on a pyruvic acid thiosemicarbazone ligand with the lithium cation Li[Fe III (thpy) 2 ]·3H 2 O ( 1 ) has been synthesized and characterized by FTIR spectroscopy, powder and single crystal X-ray diffraction, direct current magnetic susceptibility measurements, an...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2023-02, Vol.52 (6), p.186-1819
Hauptverfasser:	Blagov, Maxim A, Spitsyna, Nataliya G, Ovanesyan, Nikolai S, Lobach, Anatolii S, Zorina, Leokadiya V, Simonov, Sergey V, Zakharov, Konstantin V, Vasiliev, Alexander N
Format:	Artikel
Sprache:	eng
Schlagworte:	Anion exchanging Antiferromagnetism Cations Coupling (molecular) Crossovers Crystal structure Dimers Direct current Hydrogen bonding Hydrogen bonds Iron Iron 57 Ligands Lithium Magnetic measurement Magnetic permeability Magnetic properties Molecular structure Mossbauer spectroscopy Nitrogen tetroxide Single crystals Spectrum analysis Stabilization Temperature dependence
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