Effect of Water Deuteration on Protein Electron Transfer

Traditional theories of long-range protein electron transfer describe the reaction rate in terms of the tunneling distance and the reaction free energy. They do not recognize two physical effects: (i) local wetting of the active site by hydration water and (ii) protein identity affecting the rate th...

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Veröffentlicht in:	The journal of physical chemistry letters 2023-01, Vol.14 (3), p.723-729
Hauptverfasser:	Mostajabi Sarhangi, Setare, Matyushov, Dmitry V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Deuterium Oxide Electron Transport Electrons Physical Insights into Materials and Molecular Properties Proteins - chemistry Water - chemistry
Online-Zugang:	Volltext
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