Magnetic properties of a soft magnetic elastomer based on antioxidant magnetic composite particles and a water-soluble polymer matrix

A soft magnetic elastomer, called a magnetorheological elastomer (MRE), based on a polyacrylamide (PAM) modified carbonyl iron particle (P-CIP) composite and a water-soluble PAM matrix was designed and prepared by the chemical polymerization and crosslinking method. P-CIPs were synthesized by the po...

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Veröffentlicht in:Soft matter 2023-02, Vol.19 (5), p.18-116
Hauptverfasser: Si, Xiaodong, Luo, Mingliang, Li, Mingzhong, Ma, Yuben, Huang, Yige, Ge, Yunzhi
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container_start_page 18
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creator Si, Xiaodong
Luo, Mingliang
Li, Mingzhong
Ma, Yuben
Huang, Yige
Ge, Yunzhi
description A soft magnetic elastomer, called a magnetorheological elastomer (MRE), based on a polyacrylamide (PAM) modified carbonyl iron particle (P-CIP) composite and a water-soluble PAM matrix was designed and prepared by the chemical polymerization and crosslinking method. P-CIPs were synthesized by the polymerization of an acrylamide monomer on the CIP surface to improve the oxidation resistance of CIPs and the interaction between the particles and polymer matrix in the MRE. The results obtained from infrared spectroscopy, scanning electron microscopy (SEM) and thermogravimetric analysis (TGA) (in a nitrogen atmosphere) show that the coating effect of the polymer on the particle surface is very good. TGA (in an air atmosphere) curves indicate that the P-CIPs show strong oxidation resistance. Meanwhile, the test results obtained for the magnetic properties show that the MRE with P-CIPs has a saturation magnetization (94.7 emu g −1 ), a relative magnetorheological effect (687.5%), and a Payne effect factor (92%) under the action of a strong magnetic field (1 T). It was also clearly found that these properties are enhanced with increasing magnetic field intensity. Furthermore, the chain effect of magnetic particles under a magnetic field, the strong particle-matrix interaction and its breakdown process with increasing shear strain were discussed in this work. A soft magnetic elastomer, called a magnetorheological elastomer (MRE), based on a polyacrylamide (PAM) modified carbonyl iron particle (P-CIP) composite and a water-soluble PAM matrix was designed and prepared.
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P-CIPs were synthesized by the polymerization of an acrylamide monomer on the CIP surface to improve the oxidation resistance of CIPs and the interaction between the particles and polymer matrix in the MRE. The results obtained from infrared spectroscopy, scanning electron microscopy (SEM) and thermogravimetric analysis (TGA) (in a nitrogen atmosphere) show that the coating effect of the polymer on the particle surface is very good. TGA (in an air atmosphere) curves indicate that the P-CIPs show strong oxidation resistance. Meanwhile, the test results obtained for the magnetic properties show that the MRE with P-CIPs has a saturation magnetization (94.7 emu g −1 ), a relative magnetorheological effect (687.5%), and a Payne effect factor (92%) under the action of a strong magnetic field (1 T). It was also clearly found that these properties are enhanced with increasing magnetic field intensity. Furthermore, the chain effect of magnetic particles under a magnetic field, the strong particle-matrix interaction and its breakdown process with increasing shear strain were discussed in this work. 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Furthermore, the chain effect of magnetic particles under a magnetic field, the strong particle-matrix interaction and its breakdown process with increasing shear strain were discussed in this work. 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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Acrylamide
Atmosphere
Carbonyl compounds
Carbonyls
Coating effects
Crosslinking
Elastomers
Infrared analysis
Infrared spectroscopy
Magnetic fields
Magnetic flux
Magnetic properties
Magnetic saturation
Magnetism
Oxidation
Oxidation resistance
Particulate composites
Polyacrylamide
Polymerization
Polymers
Scanning electron microscopy
Shear strain
Thermogravimetric analysis
Water chemistry
Water soluble polymers
title Magnetic properties of a soft magnetic elastomer based on antioxidant magnetic composite particles and a water-soluble polymer matrix
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