Understanding the Organometallic Step: SO2 Insertion into Bi(III)−C(Ph) Bond

Heavier main‐group element‐catalyzed reactions provide an increasingly attractive tool to perform transformations mimicking the behaviors of transition metal catalysts. Recently, Magre and Cornella reported a Bi‐catalyzed synthesis of aryl sulfonyl fluorides, which involves a fundamental organometal...

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Veröffentlicht in:	Chemistry, an Asian journal an Asian journal, 2023-02, Vol.18 (4), p.e202201218-n/a
Hauptverfasser:	Wong, Wing Hei Marco, Guo, Xueying, Chan, Hok Tsun, Yang, Tilong, Lin, Zhenyang
Format:	Artikel
Sprache:	eng
Schlagworte:	Bismuth chemistry Catalysis Chemical reactions Chemical synthesis Chemistry Coordination DFT calculations Fluorides Insertion Main group catalysis Principal interacting orbital (PIO) Structure and bonding analysis Transition metals
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