Photoinduced Catalytic Organic‐Hydride Transfer to CO2 Mediated with Ruthenium Complexes as NAD+/NADH Redox Couple Models
The catalytic organic‐hydride transfer to CO2 was first achieved through the photoinduced two‐electron reduction of the [Ru(bpy)2(pbn)]2+/[Ru(bpy)2(pbnHH)]2+ (bpy=2,2’‐bipyridine, pbn=2‐(pyridin‐2‐yl)benzo[b]‐1,5‐naphthyridine, and pbnHH=2‐(pyridin‐2‐yl)‐5,10‐dihydrobenzo[b]‐1,5‐naphthyridine) redox...
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| Veröffentlicht in: | ChemSusChem 2023-03, Vol.16 (6), p.e202300032-n/a |
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| creator | Kinoshita, Yusuke Deromachi, Nagisa Kajiwara, Takashi Koizumi, Take‐aki Kitagawa, Susumu Tamiaki, Hitoshi Tanaka, Koji |
| description | The catalytic organic‐hydride transfer to CO2 was first achieved through the photoinduced two‐electron reduction of the [Ru(bpy)2(pbn)]2+/[Ru(bpy)2(pbnHH)]2+ (bpy=2,2’‐bipyridine, pbn=2‐(pyridin‐2‐yl)benzo[b]‐1,5‐naphthyridine, and pbnHH=2‐(pyridin‐2‐yl)‐5,10‐dihydrobenzo[b]‐1,5‐naphthyridine) redox couple in the presence of 1,3‐dimethyl‐2‐phenyl‐2,3‐dihydro‐1H‐benzo[d]imidazole (BIH). The active species for the catalytic hydride transfer to carbon dioxide giving formate is [Ru(bpy)(bpy⋅−)(pbnHH)]+ formed by one‐electron reduction of [Ru(bpy)2(pbnHH)]2+ with BI⋅.
The first catalytic organic‐hydride transfer to CO2 is achieved through the photoinduced two‐electron reduction of [Ru(bpy)2(pbn)]2+ and the subsequent one‐electron reduction of the resultant [Ru(bpy)2(pbnHH)]2+ with generation of [Ru(bpy)(bpy⋅−)(pbnHH)]+ as the active catalyst in the presence of BIH in H2O/CH3CN. |
| doi_str_mv | 10.1002/cssc.202300032 |
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The first catalytic organic‐hydride transfer to CO2 is achieved through the photoinduced two‐electron reduction of [Ru(bpy)2(pbn)]2+ and the subsequent one‐electron reduction of the resultant [Ru(bpy)2(pbnHH)]2+ with generation of [Ru(bpy)(bpy⋅−)(pbnHH)]+ as the active catalyst in the presence of BIH in H2O/CH3CN.</description><identifier>ISSN: 1864-5631</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.202300032</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Carbon dioxide ; formate ; hydride transfer ; Hydrides ; Imidazole ; Nicotinamide adenine dinucleotide ; organic hydride ; photoreduction ; Reduction ; ruthenium complex ; Ruthenium compounds</subject><ispartof>ChemSusChem, 2023-03, Vol.16 (6), p.e202300032-n/a</ispartof><rights>2023 The Authors. ChemSusChem published by Wiley-VCH GmbH</rights><rights>2023. This article is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0003-4797-0349 ; 0000-0001-7681-2644</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcssc.202300032$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcssc.202300032$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Kinoshita, Yusuke</creatorcontrib><creatorcontrib>Deromachi, Nagisa</creatorcontrib><creatorcontrib>Kajiwara, Takashi</creatorcontrib><creatorcontrib>Koizumi, Take‐aki</creatorcontrib><creatorcontrib>Kitagawa, Susumu</creatorcontrib><creatorcontrib>Tamiaki, Hitoshi</creatorcontrib><creatorcontrib>Tanaka, Koji</creatorcontrib><title>Photoinduced Catalytic Organic‐Hydride Transfer to CO2 Mediated with Ruthenium Complexes as NAD+/NADH Redox Couple Models</title><title>ChemSusChem</title><description>The catalytic organic‐hydride transfer to CO2 was first achieved through the photoinduced two‐electron reduction of the [Ru(bpy)2(pbn)]2+/[Ru(bpy)2(pbnHH)]2+ (bpy=2,2’‐bipyridine, pbn=2‐(pyridin‐2‐yl)benzo[b]‐1,5‐naphthyridine, and pbnHH=2‐(pyridin‐2‐yl)‐5,10‐dihydrobenzo[b]‐1,5‐naphthyridine) redox couple in the presence of 1,3‐dimethyl‐2‐phenyl‐2,3‐dihydro‐1H‐benzo[d]imidazole (BIH). The active species for the catalytic hydride transfer to carbon dioxide giving formate is [Ru(bpy)(bpy⋅−)(pbnHH)]+ formed by one‐electron reduction of [Ru(bpy)2(pbnHH)]2+ with BI⋅.
The first catalytic organic‐hydride transfer to CO2 is achieved through the photoinduced two‐electron reduction of [Ru(bpy)2(pbn)]2+ and the subsequent one‐electron reduction of the resultant [Ru(bpy)2(pbnHH)]2+ with generation of [Ru(bpy)(bpy⋅−)(pbnHH)]+ as the active catalyst in the presence of BIH in H2O/CH3CN.</description><subject>Carbon dioxide</subject><subject>formate</subject><subject>hydride transfer</subject><subject>Hydrides</subject><subject>Imidazole</subject><subject>Nicotinamide adenine dinucleotide</subject><subject>organic hydride</subject><subject>photoreduction</subject><subject>Reduction</subject><subject>ruthenium complex</subject><subject>Ruthenium compounds</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNpdkU1Lw0AQhoMoWKtXzwteBEm7u0k2ybHEjwqtlbaCt7DdnbVb0mzdTWiDF3-Cv9FfYorSg5f54H1mmOH1vEuCewRj2hfOiR7FNMAYB_TI65CEhX7EwtfjQx2QU-_MuRXGDKeMdbyP56WpjC5lLUCijFe8aCot0MS-8VKL78-vYSOtloDmlpdOgUWVQdmEojFIzat2aKurJZrW1RJKXa9RZtabAnbgEHfoaXB702_DEE1Bml0r1q2IxkZC4c69E8ULBxd_ueu93N_Ns6E_mjw8ZoORvwoJo34ay4BIUFGYEkwAc-BURbGAUEQyYgsWK7pgksUCA1WSSKFU-50IlQwpSZOg613_7t1Y816Dq_K1dgKKgpdgapfTmEVxHARsj179Q1emtmV7XUslKUtoxKKWSn-prS6gyTdWr7ltcoLzvRH53oj8YESezWbZoQt-AP1Qf-8</recordid><startdate>20230322</startdate><enddate>20230322</enddate><creator>Kinoshita, Yusuke</creator><creator>Deromachi, Nagisa</creator><creator>Kajiwara, Takashi</creator><creator>Koizumi, Take‐aki</creator><creator>Kitagawa, Susumu</creator><creator>Tamiaki, Hitoshi</creator><creator>Tanaka, Koji</creator><general>Wiley Subscription Services, Inc</general><scope>24P</scope><scope>WIN</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-4797-0349</orcidid><orcidid>https://orcid.org/0000-0001-7681-2644</orcidid></search><sort><creationdate>20230322</creationdate><title>Photoinduced Catalytic Organic‐Hydride Transfer to CO2 Mediated with Ruthenium Complexes as NAD+/NADH Redox Couple Models</title><author>Kinoshita, Yusuke ; Deromachi, Nagisa ; Kajiwara, Takashi ; Koizumi, Take‐aki ; Kitagawa, Susumu ; Tamiaki, Hitoshi ; Tanaka, Koji</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-j4162-97d31def549101e0aea2f57ce4c5d56b67f2b6d67c0e2fd1dcff609c4fd421983</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Carbon dioxide</topic><topic>formate</topic><topic>hydride transfer</topic><topic>Hydrides</topic><topic>Imidazole</topic><topic>Nicotinamide adenine dinucleotide</topic><topic>organic hydride</topic><topic>photoreduction</topic><topic>Reduction</topic><topic>ruthenium complex</topic><topic>Ruthenium compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kinoshita, Yusuke</creatorcontrib><creatorcontrib>Deromachi, Nagisa</creatorcontrib><creatorcontrib>Kajiwara, Takashi</creatorcontrib><creatorcontrib>Koizumi, Take‐aki</creatorcontrib><creatorcontrib>Kitagawa, Susumu</creatorcontrib><creatorcontrib>Tamiaki, Hitoshi</creatorcontrib><creatorcontrib>Tanaka, Koji</creatorcontrib><collection>Wiley Online Library Open Access</collection><collection>Wiley Online Library (Open Access Collection)</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kinoshita, Yusuke</au><au>Deromachi, Nagisa</au><au>Kajiwara, Takashi</au><au>Koizumi, Take‐aki</au><au>Kitagawa, Susumu</au><au>Tamiaki, Hitoshi</au><au>Tanaka, Koji</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photoinduced Catalytic Organic‐Hydride Transfer to CO2 Mediated with Ruthenium Complexes as NAD+/NADH Redox Couple Models</atitle><jtitle>ChemSusChem</jtitle><date>2023-03-22</date><risdate>2023</risdate><volume>16</volume><issue>6</issue><spage>e202300032</spage><epage>n/a</epage><pages>e202300032-n/a</pages><issn>1864-5631</issn><eissn>1864-564X</eissn><abstract>The catalytic organic‐hydride transfer to CO2 was first achieved through the photoinduced two‐electron reduction of the [Ru(bpy)2(pbn)]2+/[Ru(bpy)2(pbnHH)]2+ (bpy=2,2’‐bipyridine, pbn=2‐(pyridin‐2‐yl)benzo[b]‐1,5‐naphthyridine, and pbnHH=2‐(pyridin‐2‐yl)‐5,10‐dihydrobenzo[b]‐1,5‐naphthyridine) redox couple in the presence of 1,3‐dimethyl‐2‐phenyl‐2,3‐dihydro‐1H‐benzo[d]imidazole (BIH). The active species for the catalytic hydride transfer to carbon dioxide giving formate is [Ru(bpy)(bpy⋅−)(pbnHH)]+ formed by one‐electron reduction of [Ru(bpy)2(pbnHH)]2+ with BI⋅.
The first catalytic organic‐hydride transfer to CO2 is achieved through the photoinduced two‐electron reduction of [Ru(bpy)2(pbn)]2+ and the subsequent one‐electron reduction of the resultant [Ru(bpy)2(pbnHH)]2+ with generation of [Ru(bpy)(bpy⋅−)(pbnHH)]+ as the active catalyst in the presence of BIH in H2O/CH3CN.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/cssc.202300032</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-4797-0349</orcidid><orcidid>https://orcid.org/0000-0001-7681-2644</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Carbon dioxide formate hydride transfer Hydrides Imidazole Nicotinamide adenine dinucleotide organic hydride photoreduction Reduction ruthenium complex Ruthenium compounds |
| title | Photoinduced Catalytic Organic‐Hydride Transfer to CO2 Mediated with Ruthenium Complexes as NAD+/NADH Redox Couple Models |
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