Synthesis of benzo[b][1,5]diazocin-6(5H)-one derivatives via the Cu-catalysed oxidative cyclization of 2-aryl-1H-indoles with 1,1-enediamines

A novel protocol for the synthesis of highly functionalized benzo[b][1,5]diazocin-6(5H)-one derivatives (BDCOs, 4 and 5) from 2-aryl-1H-indoles and 1,1-enediamines was developed via a complex cascade of reactions including regioselective free radical oxidation, the 1,2-addition of imine, imine–enami...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2023-01, Vol.59 (9), p.1217-1220
Hauptverfasser:	Yi-Hua, Chen, Yang, Jing, Zi-Han, Lu, Ke-Hua, Zhao, Qi-Ying, Xie, Sheng-Jiao, Yan
Format:	Artikel
Sprache:	eng
Schlagworte:	Argon Aromatic compounds Cascade chemical reactions Chemical reactions Chemical synthesis Combinatorial analysis Free radicals Indoles Oxidation Oxidizing agents Refluxing Regioselectivity Substrates Toluene
Online-Zugang:	Volltext
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