Plasma deposition and characterization of acrylic acid thin film on ZnO nanoparticles

Acrylic acid polymer thin films were deposited on the surfaces of nanoparticles of ZnO using a plasma polymerization treatment. The average size of nanoparticles was on the order of 50 nm in irregular shapes. High-resolution transmission electron microscopy (HRTEM) experiments showed that an extreme...

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Veröffentlicht in:Journal of materials research 2002-10, Vol.17 (10), p.2555-2560
Hauptverfasser: Shi, Donglu, He, Peng, Lian, Jie, Wang, Lumin, van Ooij, Wim J.
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He, Peng
Lian, Jie
Wang, Lumin
van Ooij, Wim J.
description Acrylic acid polymer thin films were deposited on the surfaces of nanoparticles of ZnO using a plasma polymerization treatment. The average size of nanoparticles was on the order of 50 nm in irregular shapes. High-resolution transmission electron microscopy (HRTEM) experiments showed that an extremely thin film of the acrylic acid layer (15 nm) was uniformly deposited on the surfaces of the nanoparticles. The HRTEM results were confirmed by time-of-flight secondary ion mass spectroscopy. The effect of plasma power on the polyacrylic thin film was studied by Fourier transform infrared experiments. The deposition mechanisms and the effects of plasma treatment parameters are discussed.
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