Another approach to the Gibbs–Thomson equation and the melting point of polymers and oligomers
The common Gibbs–Thomson equation, widely used to explain the melting temperature of lamella crystals, is based on a given heat of fusion and a given surface free energy and the size (thickness) of the crystal. With this equation it is not possible to explain the, compared to the thickness of the cr...
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Veröffentlicht in: | Polymer (Guilford) 2002-08, Vol.43 (17), p.4689-4698 |
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Sprache: | eng |
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