Transition‐Metal‐Free Intermolecular Hydrocarbonation of Styrenes Mediated by NaH/1,10‐Phenanthroline

A transition‐metal‐free intermolecular coupling reaction of halocompounds with styrenes in the presence of NaH and 1,10‐phenanthroline was developed. This reaction afforded hydrocarbonated products with complete anti‐Markovnikov selectivity. The method allows the use of a wide range of halocompounds...

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Veröffentlicht in:	Chemistry : a European journal 2023-03, Vol.29 (18), p.e202203143-n/a
Hauptverfasser:	Nozawa‐Kumada, Kanako, Onuma, So, Ono, Kanako, Kumagai, Tomohiro, Iwakawa, Yuki, Sato, Katsuhiko, Shigeno, Masanori, Kondo, Yoshinori
Format:	Artikel
Sprache:	eng
Schlagworte:	carboradical Chemistry Functional groups Halides hydrocarbonation single-electron-transfer sodium hydride Styrenes
Online-Zugang:	Volltext
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