Intercalation and exfoliation behavior of epoxy resin/curing agent/montmorillonite nanocomposite
The epoxy resin/curing agent/montmorillonite nanocomposite was prepared by a casting and curing process. The intercalation and exfoliation behaviors of epoxy resin in the presence of organophilic montmorillonite were investigated by X‐ray diffraction (XRD) and dynamic mechanical thermal analysis (DM...
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| Veröffentlicht in: | Journal of applied polymer science 2002-04, Vol.84 (4), p.842-849 |
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| container_title | Journal of applied polymer science |
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| creator | Xu, Wei-Bing Bao, Su-Ping He, Ping-Sheng |
| description | The epoxy resin/curing agent/montmorillonite nanocomposite was prepared by a casting and curing process. The intercalation and exfoliation behaviors of epoxy resin in the presence of organophilic montmorillonite were investigated by X‐ray diffraction (XRD) and dynamic mechanical thermal analysis (DMTA). For the diethylenetriamine curing agent, the intercalated nanocomposite was obtained; and the exfoliated nanocomposite would be formed for tung oil anhydride curing agent. The curing condition does not affect the resulting kind of composite, both intercalation or exfoliation. For intercalated nanocomposite, the glass transition temperature Tg, measured by DMTA and affected by the curing temperature of matrix epoxy resin is corresponded to that of epoxy resin without a gallery. The α′ peak of the loss tangent will disappear if adding montmorillonite into the composite. It was also found that the Tg of the exfoliated nanocomposite decreases with increasing montmorillonite loading. © 2002 John Wiley & Sons, Inc. J Appl Polym Sci 84: 842–849, 2002; DOI 10.1002/app.10354 |
| doi_str_mv | 10.1002/app.10354 |
| format | Article |
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The intercalation and exfoliation behaviors of epoxy resin in the presence of organophilic montmorillonite were investigated by X‐ray diffraction (XRD) and dynamic mechanical thermal analysis (DMTA). For the diethylenetriamine curing agent, the intercalated nanocomposite was obtained; and the exfoliated nanocomposite would be formed for tung oil anhydride curing agent. The curing condition does not affect the resulting kind of composite, both intercalation or exfoliation. For intercalated nanocomposite, the glass transition temperature Tg, measured by DMTA and affected by the curing temperature of matrix epoxy resin is corresponded to that of epoxy resin without a gallery. The α′ peak of the loss tangent will disappear if adding montmorillonite into the composite. It was also found that the Tg of the exfoliated nanocomposite decreases with increasing montmorillonite loading. © 2002 John Wiley & Sons, Inc. J Appl Polym Sci 84: 842–849, 2002; DOI 10.1002/app.10354</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.10354</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>New York: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; clay ; Composites ; Exact sciences and technology ; Forms of application and semi-finished materials ; glass transition ; nanocomposites ; Polymer industry, paints, wood ; resin ; Technology of polymers ; X-ray</subject><ispartof>Journal of applied polymer science, 2002-04, Vol.84 (4), p.842-849</ispartof><rights>Copyright © 2002 Wiley Periodicals, Inc.</rights><rights>2002 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3664-2cdd2f7c9f039d5853769b325cee39b715a998b9b99e4dacdbd96f25c15a00d63</citedby><cites>FETCH-LOGICAL-c3664-2cdd2f7c9f039d5853769b325cee39b715a998b9b99e4dacdbd96f25c15a00d63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.10354$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.10354$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27928,27929,45578,45579</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=13517067$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Xu, Wei-Bing</creatorcontrib><creatorcontrib>Bao, Su-Ping</creatorcontrib><creatorcontrib>He, Ping-Sheng</creatorcontrib><title>Intercalation and exfoliation behavior of epoxy resin/curing agent/montmorillonite nanocomposite</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The epoxy resin/curing agent/montmorillonite nanocomposite was prepared by a casting and curing process. The intercalation and exfoliation behaviors of epoxy resin in the presence of organophilic montmorillonite were investigated by X‐ray diffraction (XRD) and dynamic mechanical thermal analysis (DMTA). For the diethylenetriamine curing agent, the intercalated nanocomposite was obtained; and the exfoliated nanocomposite would be formed for tung oil anhydride curing agent. The curing condition does not affect the resulting kind of composite, both intercalation or exfoliation. For intercalated nanocomposite, the glass transition temperature Tg, measured by DMTA and affected by the curing temperature of matrix epoxy resin is corresponded to that of epoxy resin without a gallery. The α′ peak of the loss tangent will disappear if adding montmorillonite into the composite. It was also found that the Tg of the exfoliated nanocomposite decreases with increasing montmorillonite loading. © 2002 John Wiley & Sons, Inc. J Appl Polym Sci 84: 842–849, 2002; DOI 10.1002/app.10354</description><subject>Applied sciences</subject><subject>clay</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>glass transition</subject><subject>nanocomposites</subject><subject>Polymer industry, paints, wood</subject><subject>resin</subject><subject>Technology of polymers</subject><subject>X-ray</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNp1kLFO5DAURS20SMwCBX-QhpW2CGPHsROXLAMDEoIpQCAa4zgvYDaxg52Bmb_HEHapqOyne-4pLkJ7BB8QjLOp6vv4oSzfQBOCRZHmPCt_oEnMSFoKwbbQzxCeMCaEYT5B92d2AK9VqwbjbKJsncCqca0Z7woe1YtxPnFNAr1brRMPwdipXnpjHxL1AHaYds4OnfOmbZ01AyRWWadd17sQrx202ag2wO7nu42uT46vjk7T88v52dHheaop53ma6brOmkKLBlNRs5LRgouKZkwDUFEVhCkhykpUQkBeK11XteBNjGOAcc3pNvo1envvnpcQBtmZoKFtlQW3DDIrOM4JZRH8PYLauxA8NLL3plN-LQmW7xvKuKH82DCy-59SFeJGjVdWm_BVoIwUmBeRm47cq2lh_b1QHi4W_8zp2DBhgNX_hvJ_ZfQVTN5czOXdn_nipJzdyhl9A73VkdM</recordid><startdate>20020425</startdate><enddate>20020425</enddate><creator>Xu, Wei-Bing</creator><creator>Bao, Su-Ping</creator><creator>He, Ping-Sheng</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20020425</creationdate><title>Intercalation and exfoliation behavior of epoxy resin/curing agent/montmorillonite nanocomposite</title><author>Xu, Wei-Bing ; Bao, Su-Ping ; He, Ping-Sheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3664-2cdd2f7c9f039d5853769b325cee39b715a998b9b99e4dacdbd96f25c15a00d63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Applied sciences</topic><topic>clay</topic><topic>Composites</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>glass transition</topic><topic>nanocomposites</topic><topic>Polymer industry, paints, wood</topic><topic>resin</topic><topic>Technology of polymers</topic><topic>X-ray</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Wei-Bing</creatorcontrib><creatorcontrib>Bao, Su-Ping</creatorcontrib><creatorcontrib>He, Ping-Sheng</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Wei-Bing</au><au>Bao, Su-Ping</au><au>He, Ping-Sheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Intercalation and exfoliation behavior of epoxy resin/curing agent/montmorillonite nanocomposite</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2002-04-25</date><risdate>2002</risdate><volume>84</volume><issue>4</issue><spage>842</spage><epage>849</epage><pages>842-849</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The epoxy resin/curing agent/montmorillonite nanocomposite was prepared by a casting and curing process. The intercalation and exfoliation behaviors of epoxy resin in the presence of organophilic montmorillonite were investigated by X‐ray diffraction (XRD) and dynamic mechanical thermal analysis (DMTA). For the diethylenetriamine curing agent, the intercalated nanocomposite was obtained; and the exfoliated nanocomposite would be formed for tung oil anhydride curing agent. The curing condition does not affect the resulting kind of composite, both intercalation or exfoliation. For intercalated nanocomposite, the glass transition temperature Tg, measured by DMTA and affected by the curing temperature of matrix epoxy resin is corresponded to that of epoxy resin without a gallery. The α′ peak of the loss tangent will disappear if adding montmorillonite into the composite. It was also found that the Tg of the exfoliated nanocomposite decreases with increasing montmorillonite loading. © 2002 John Wiley & Sons, Inc. J Appl Polym Sci 84: 842–849, 2002; DOI 10.1002/app.10354</abstract><cop>New York</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.10354</doi><tpages>8</tpages></addata></record> |
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| subjects | Applied sciences clay Composites Exact sciences and technology Forms of application and semi-finished materials glass transition nanocomposites Polymer industry, paints, wood resin Technology of polymers X-ray |
| title | Intercalation and exfoliation behavior of epoxy resin/curing agent/montmorillonite nanocomposite |
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