Substrate-Gated Transformation of a Pre-Catalyst into an Iron-Hydride Intermediate [(NO)2(CO)Fe(μ-H)Fe(CO)(NO)2]− for Catalytic Dehydrogenation of Dimethylamine Borane

Continued efforts are made on the development of earth-abundant metal catalysts for dehydrogenation/hydrolysis of amine boranes. In this study, complex [K-18-crown-6-ether]­[(NO)2Fe­(μ-MePyr)­(μ-CO)­Fe­(NO)2] (3-K-crown, MePyr = 3-methylpyrazolate) was explored as a pre-catalyst for the dehydrogenat...

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Veröffentlicht in:	Inorganic chemistry 2023-01, Vol.62 (2), p.769-781
Hauptverfasser:	Tseng, Yu-Ting, Pelmenschikov, Vladimir, Iffland-Mühlhaus, Linda, Calabrese, Donato, Chang, Yu-Che, Laun, Konstantin, Pao, Chih-Wen, Sergueev, Ilya, Yoda, Yoshitaka, Liaw, Wen-Feng, Chen, Chien-Hong, Hsu, I-Jui, Apfel, Ulf-Peter, Caserta, Giorgio, Lauterbach, Lars, Lu, Tsai-Te
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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