Binder-free cupric-ion containing zinc sulfide nanoplates-like structure for flexible energy storage devices

Researchers have been enthusiastic about developing high-performance electrode materials based on metal chalcogenides for energy storage applications. Herein, we developed cupric ion-containing zinc sulfide (ZnS:Cu) nanoplates by using a solvothermal approach. The as-synthesized ZnS:Cu nanoplates el...

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Veröffentlicht in:Chemosphere (Oxford) 2023-02, Vol.314, p.137660-137660, Article 137660
Hauptverfasser: Hussain, Iftikhar, Shaheen, Irum, Ahmad, Rabia, Ali, Ijaz, Hussain, Khurshid, Hussain, Sayed Sajid, Alsaiari, Norah Salem, Katubi, Khadijah Mohammedsaleh, Eldin, Sayed M., Ansari, Mohd Zahid
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container_title Chemosphere (Oxford)
container_volume 314
creator Hussain, Iftikhar
Shaheen, Irum
Ahmad, Rabia
Ali, Ijaz
Hussain, Khurshid
Hussain, Sayed Sajid
Alsaiari, Norah Salem
Katubi, Khadijah Mohammedsaleh
Eldin, Sayed M.
Ansari, Mohd Zahid
description Researchers have been enthusiastic about developing high-performance electrode materials based on metal chalcogenides for energy storage applications. Herein, we developed cupric ion-containing zinc sulfide (ZnS:Cu) nanoplates by using a solvothermal approach. The as-synthesized ZnS:Cu nanoplates electrode was characterized and analyzed by using XRD, SEM, TEM, EDS, and XPS. The binder-free flexible ZnS:Cu nanoplates exhibited excellent specific capacitance of 545 F g−1 at a current density of 1 A g−1. The CV and GCD measurements revealed that the specific capacitance was mainly attributed to the Faradaic redox mechanism. Further, the binder-free flexible ZnS:Cu nanoplates electrode retained 87.4% along with excellent Coulombic efficiency (99%) after 5000 cycles. The binder-free flexible ZnS:Cu nanoplates exhibited excellent conductivity, specific capacitance, and stability which are beneficial in energy storage systems. These findings will also open new horizons amongst material scientists toward the new direction of electrode development. [Display omitted] •Cupric ion-containing zinc sulfide (ZnS:Cu) nanoplates was reported.•The ZnS:Cu nanoplate electrode exhibited capacity of 218 C g−1.•The ZnS: Cu electrode retained 87.4% cyclic stability after 5000 cycles.•The composite exhibited 99% Coulombic efficiency.
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Herein, we developed cupric ion-containing zinc sulfide (ZnS:Cu) nanoplates by using a solvothermal approach. The as-synthesized ZnS:Cu nanoplates electrode was characterized and analyzed by using XRD, SEM, TEM, EDS, and XPS. The binder-free flexible ZnS:Cu nanoplates exhibited excellent specific capacitance of 545 F g−1 at a current density of 1 A g−1. The CV and GCD measurements revealed that the specific capacitance was mainly attributed to the Faradaic redox mechanism. Further, the binder-free flexible ZnS:Cu nanoplates electrode retained 87.4% along with excellent Coulombic efficiency (99%) after 5000 cycles. The binder-free flexible ZnS:Cu nanoplates exhibited excellent conductivity, specific capacitance, and stability which are beneficial in energy storage systems. These findings will also open new horizons amongst material scientists toward the new direction of electrode development. [Display omitted] •Cupric ion-containing zinc sulfide (ZnS:Cu) nanoplates was reported.•The ZnS:Cu nanoplate electrode exhibited capacity of 218 C g−1.•The ZnS: Cu electrode retained 87.4% cyclic stability after 5000 cycles.•The composite exhibited 99% Coulombic efficiency.</description><identifier>ISSN: 0045-6535</identifier><identifier>EISSN: 1879-1298</identifier><identifier>DOI: 10.1016/j.chemosphere.2022.137660</identifier><identifier>PMID: 36581122</identifier><language>eng</language><publisher>England: Elsevier Ltd</publisher><subject>Capacity ; Cu-containing ZnS nanoplates ; Electric Capacitance ; Electrode ; Excipients ; Nanomaterials ; Zinc ; Zinc Compounds</subject><ispartof>Chemosphere (Oxford), 2023-02, Vol.314, p.137660-137660, Article 137660</ispartof><rights>2022 Elsevier Ltd</rights><rights>Copyright © 2022 Elsevier Ltd. 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[Display omitted] •Cupric ion-containing zinc sulfide (ZnS:Cu) nanoplates was reported.•The ZnS:Cu nanoplate electrode exhibited capacity of 218 C g−1.•The ZnS: Cu electrode retained 87.4% cyclic stability after 5000 cycles.•The composite exhibited 99% Coulombic efficiency.</abstract><cop>England</cop><pub>Elsevier Ltd</pub><pmid>36581122</pmid><doi>10.1016/j.chemosphere.2022.137660</doi><tpages>1</tpages></addata></record>
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subjects Capacity
Cu-containing ZnS nanoplates
Electric Capacitance
Electrode
Excipients
Nanomaterials
Zinc
Zinc Compounds
title Binder-free cupric-ion containing zinc sulfide nanoplates-like structure for flexible energy storage devices
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