On the properties and functionality of ultra-thin diamond related protective coatings used in optical systems

In this work we investigate the applicability of sputtered developed films belonging to diamond related materials, like amorphous carbon (a-C), carbon nitride (CN x ), and boron nitride (BN x ) films, as protective overcoatings of optical systems. Their suitability is defined by the combination of o...

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Veröffentlicht in:Sensors and actuators. A, Physical Physical, 2002-04, Vol.99 (1), p.35-40
Hauptverfasser: Gioti, M., Logothetidis, S., Charitidis, C., Panayiotatos, Y., Varsano, I.
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container_issue 1
container_start_page 35
container_title Sensors and actuators. A, Physical
container_volume 99
creator Gioti, M.
Logothetidis, S.
Charitidis, C.
Panayiotatos, Y.
Varsano, I.
description In this work we investigate the applicability of sputtered developed films belonging to diamond related materials, like amorphous carbon (a-C), carbon nitride (CN x ), and boron nitride (BN x ) films, as protective overcoatings of optical systems. Their suitability is defined by the combination of optical transparency (low absorption in the VIS energy region) with the high hardness and wear resistant character of the coating. The optical systems of our interest are electron-beam evaporated TiO 2/SiO 2 multi-layered coatings grown on polymeric substrates, which exhibit the optimum antireflective (AR) optical behavior but low wear durability and hardness. Within this research frame it was found a considerable enhancement of hardness of the AR optical coatings, which were studied by nanoindentation measurements, when an ultra-thin (∼100 Å) protective coating either of a-C, CN x or BN x is grown on top of them. In order to define which coating is the most proper one for such applications we extensively studied by spectroscopic ellipsometry the dielectric response and the optical properties of the developed films, as well as the combined reflectivity and optical response of the complete systems (AR/protective coatings).
doi_str_mv 10.1016/S0924-4247(01)00887-1
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subjects Antireflective coatings
Boron nitride films
Carbon-based films
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Insulators
Nanoindentation studies
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical properties of specific thin films
Other nonelectronic physical properties
Physical properties of thin films, nonelectronic
Physics
Protective coatings
Spectroscopic ellipsometry
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
title On the properties and functionality of ultra-thin diamond related protective coatings used in optical systems
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