Co-torrefaction of corncob and waste cooking oil coupled with fast co-pyrolysis for bio-oil production
[Display omitted] •A new idea for hydrocarbon production by co-torrefaction coupled with co-pyrolysis.•Hydrogen in oil-bath co-torrefied corncob increased from 5.21 wt% to 6.12 wt%.•Average activation energy of oil-bath co-torrefied corncob was 164.29 kJ/mol.•Oil-bath co-torrefaction residual was mo...
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Veröffentlicht in: | Bioresource technology 2023-02, Vol.370, p.128529-128529, Article 128529 |
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creator | Wu, Qiuhao Zhang, Letian Ke, Linyao Zhang, Qi Cui, Xian Fan, Liangliang Dai, Anqi Xu, Chuangxin Zhang, Qihang Bob, Krik Zou, Rongge Liu, Yuhuan Ruan, Roger Wang, Yunpu |
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•A new idea for hydrocarbon production by co-torrefaction coupled with co-pyrolysis.•Hydrogen in oil-bath co-torrefied corncob increased from 5.21 wt% to 6.12 wt%.•Average activation energy of oil-bath co-torrefied corncob was 164.29 kJ/mol.•Oil-bath co-torrefaction residual was more suitable for bio-oil production.•Torrefaction temperature has the greatest effect on pyrolysis bio-oil composition.
Lignocellulosic biomass is a rich source of fixed renewable carbon and a promising alternative to fossil sources. However, low effective hydrogen to carbon ratio limits its applications. This work studied the influence of oil-bath co-torrefaction of corncob and waste cooking oil for co-pyrolysis. It was compared with dry torrefaction and hydrothermal wet torrefaction firstly. Residual of oil-bath co-torrefaction were the highest of 97.01 %. Oil-bath co-torrefaction could maximize hydrogen atoms retention in corncob, which has a positive significance for deoxygenation during pyrolysis. Oil-bath co-torrefaction could also reduce the average activation energy required for corncob decomposition, while it was increased with dry torrefaction. Oil-bath co-torrefaction coupled with co-pyrolysis was more suitable for hydrocarbon-rich bio-oil production. Oil-bath co-torrefaction temperature had the greatest influence on bio-oil composition. High pressure promoted formation of the CC double bond and degradation of lignin, which further promoted the formation of monocyclic aromatics in bio-oil. |
doi_str_mv | 10.1016/j.biortech.2022.128529 |
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•A new idea for hydrocarbon production by co-torrefaction coupled with co-pyrolysis.•Hydrogen in oil-bath co-torrefied corncob increased from 5.21 wt% to 6.12 wt%.•Average activation energy of oil-bath co-torrefied corncob was 164.29 kJ/mol.•Oil-bath co-torrefaction residual was more suitable for bio-oil production.•Torrefaction temperature has the greatest effect on pyrolysis bio-oil composition.
Lignocellulosic biomass is a rich source of fixed renewable carbon and a promising alternative to fossil sources. However, low effective hydrogen to carbon ratio limits its applications. This work studied the influence of oil-bath co-torrefaction of corncob and waste cooking oil for co-pyrolysis. It was compared with dry torrefaction and hydrothermal wet torrefaction firstly. Residual of oil-bath co-torrefaction were the highest of 97.01 %. Oil-bath co-torrefaction could maximize hydrogen atoms retention in corncob, which has a positive significance for deoxygenation during pyrolysis. Oil-bath co-torrefaction could also reduce the average activation energy required for corncob decomposition, while it was increased with dry torrefaction. Oil-bath co-torrefaction coupled with co-pyrolysis was more suitable for hydrocarbon-rich bio-oil production. Oil-bath co-torrefaction temperature had the greatest influence on bio-oil composition. High pressure promoted formation of the CC double bond and degradation of lignin, which further promoted the formation of monocyclic aromatics in bio-oil.</description><identifier>ISSN: 0960-8524</identifier><identifier>EISSN: 1873-2976</identifier><identifier>DOI: 10.1016/j.biortech.2022.128529</identifier><identifier>PMID: 36574887</identifier><language>eng</language><publisher>England: Elsevier Ltd</publisher><subject>Bio-oil ; Biofuels ; Biomass ; Carbon ; Co-pyrolysis ; Co-torrefaction ; Cooking ; Corncob ; Hot Temperature ; Hydrogen ; Pyrolysis ; Waste cooking oil ; Zea mays</subject><ispartof>Bioresource technology, 2023-02, Vol.370, p.128529-128529, Article 128529</ispartof><rights>2022 Elsevier Ltd</rights><rights>Copyright © 2022 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c368t-1ebc4e080ac26dba8cb8961f5c7c930e73cabe5fa7a75d4b49217c82deb5d733</citedby><cites>FETCH-LOGICAL-c368t-1ebc4e080ac26dba8cb8961f5c7c930e73cabe5fa7a75d4b49217c82deb5d733</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0960852422018624$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36574887$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wu, Qiuhao</creatorcontrib><creatorcontrib>Zhang, Letian</creatorcontrib><creatorcontrib>Ke, Linyao</creatorcontrib><creatorcontrib>Zhang, Qi</creatorcontrib><creatorcontrib>Cui, Xian</creatorcontrib><creatorcontrib>Fan, Liangliang</creatorcontrib><creatorcontrib>Dai, Anqi</creatorcontrib><creatorcontrib>Xu, Chuangxin</creatorcontrib><creatorcontrib>Zhang, Qihang</creatorcontrib><creatorcontrib>Bob, Krik</creatorcontrib><creatorcontrib>Zou, Rongge</creatorcontrib><creatorcontrib>Liu, Yuhuan</creatorcontrib><creatorcontrib>Ruan, Roger</creatorcontrib><creatorcontrib>Wang, Yunpu</creatorcontrib><title>Co-torrefaction of corncob and waste cooking oil coupled with fast co-pyrolysis for bio-oil production</title><title>Bioresource technology</title><addtitle>Bioresour Technol</addtitle><description>[Display omitted]
•A new idea for hydrocarbon production by co-torrefaction coupled with co-pyrolysis.•Hydrogen in oil-bath co-torrefied corncob increased from 5.21 wt% to 6.12 wt%.•Average activation energy of oil-bath co-torrefied corncob was 164.29 kJ/mol.•Oil-bath co-torrefaction residual was more suitable for bio-oil production.•Torrefaction temperature has the greatest effect on pyrolysis bio-oil composition.
Lignocellulosic biomass is a rich source of fixed renewable carbon and a promising alternative to fossil sources. However, low effective hydrogen to carbon ratio limits its applications. This work studied the influence of oil-bath co-torrefaction of corncob and waste cooking oil for co-pyrolysis. It was compared with dry torrefaction and hydrothermal wet torrefaction firstly. Residual of oil-bath co-torrefaction were the highest of 97.01 %. Oil-bath co-torrefaction could maximize hydrogen atoms retention in corncob, which has a positive significance for deoxygenation during pyrolysis. Oil-bath co-torrefaction could also reduce the average activation energy required for corncob decomposition, while it was increased with dry torrefaction. Oil-bath co-torrefaction coupled with co-pyrolysis was more suitable for hydrocarbon-rich bio-oil production. Oil-bath co-torrefaction temperature had the greatest influence on bio-oil composition. High pressure promoted formation of the CC double bond and degradation of lignin, which further promoted the formation of monocyclic aromatics in bio-oil.</description><subject>Bio-oil</subject><subject>Biofuels</subject><subject>Biomass</subject><subject>Carbon</subject><subject>Co-pyrolysis</subject><subject>Co-torrefaction</subject><subject>Cooking</subject><subject>Corncob</subject><subject>Hot Temperature</subject><subject>Hydrogen</subject><subject>Pyrolysis</subject><subject>Waste cooking oil</subject><subject>Zea mays</subject><issn>0960-8524</issn><issn>1873-2976</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkMtOwzAQRS0EglL4BZQlmxTbedjZgSpeUiU23Vv2eAIuaVzsBNS_x6WFLStbd-7MnTmEXDE6Y5TVN6uZcT4MCG8zTjmfMS4r3hyRCZOiyHkj6mMyoU1N86SXZ-Q8xhWltGCCn5Kzoq5EKaWYkHbu88GHgK2Gwfk-820GPvTgTaZ7m33pOGBS_LvrXzPvuvQfNx2mihvesjaVk5JvtsF32-hi1vqQpdXynXUTvB1_xl6Qk1Z3ES8P75QsH-6X86d88fL4PL9b5FDUcsgZGiiRSqqB19ZoCUY2NWsrENAUFEUB2mDVaqFFZUtTNpwJkNyiqawoiim53o9NyR8jxkGtXQTsOt2jH6Piomoo5RUtk7XeWyH4GNP9ahPcWoetYlTtEKuV-kWsdojVHnFqvDpkjGaN9q_tl2ky3O4NmA79dBhUBIc9oHUBYVDWu_8yvgH3rpLI</recordid><startdate>202302</startdate><enddate>202302</enddate><creator>Wu, Qiuhao</creator><creator>Zhang, Letian</creator><creator>Ke, Linyao</creator><creator>Zhang, Qi</creator><creator>Cui, Xian</creator><creator>Fan, Liangliang</creator><creator>Dai, Anqi</creator><creator>Xu, Chuangxin</creator><creator>Zhang, Qihang</creator><creator>Bob, Krik</creator><creator>Zou, Rongge</creator><creator>Liu, Yuhuan</creator><creator>Ruan, Roger</creator><creator>Wang, Yunpu</creator><general>Elsevier Ltd</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>202302</creationdate><title>Co-torrefaction of corncob and waste cooking oil coupled with fast co-pyrolysis for bio-oil production</title><author>Wu, Qiuhao ; Zhang, Letian ; Ke, Linyao ; Zhang, Qi ; Cui, Xian ; Fan, Liangliang ; Dai, Anqi ; Xu, Chuangxin ; Zhang, Qihang ; Bob, Krik ; Zou, Rongge ; Liu, Yuhuan ; Ruan, Roger ; Wang, Yunpu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c368t-1ebc4e080ac26dba8cb8961f5c7c930e73cabe5fa7a75d4b49217c82deb5d733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Bio-oil</topic><topic>Biofuels</topic><topic>Biomass</topic><topic>Carbon</topic><topic>Co-pyrolysis</topic><topic>Co-torrefaction</topic><topic>Cooking</topic><topic>Corncob</topic><topic>Hot Temperature</topic><topic>Hydrogen</topic><topic>Pyrolysis</topic><topic>Waste cooking oil</topic><topic>Zea mays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Qiuhao</creatorcontrib><creatorcontrib>Zhang, Letian</creatorcontrib><creatorcontrib>Ke, Linyao</creatorcontrib><creatorcontrib>Zhang, Qi</creatorcontrib><creatorcontrib>Cui, Xian</creatorcontrib><creatorcontrib>Fan, Liangliang</creatorcontrib><creatorcontrib>Dai, Anqi</creatorcontrib><creatorcontrib>Xu, Chuangxin</creatorcontrib><creatorcontrib>Zhang, Qihang</creatorcontrib><creatorcontrib>Bob, Krik</creatorcontrib><creatorcontrib>Zou, Rongge</creatorcontrib><creatorcontrib>Liu, Yuhuan</creatorcontrib><creatorcontrib>Ruan, Roger</creatorcontrib><creatorcontrib>Wang, Yunpu</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Bioresource technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Qiuhao</au><au>Zhang, Letian</au><au>Ke, Linyao</au><au>Zhang, Qi</au><au>Cui, Xian</au><au>Fan, Liangliang</au><au>Dai, Anqi</au><au>Xu, Chuangxin</au><au>Zhang, Qihang</au><au>Bob, Krik</au><au>Zou, Rongge</au><au>Liu, Yuhuan</au><au>Ruan, Roger</au><au>Wang, Yunpu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Co-torrefaction of corncob and waste cooking oil coupled with fast co-pyrolysis for bio-oil production</atitle><jtitle>Bioresource technology</jtitle><addtitle>Bioresour Technol</addtitle><date>2023-02</date><risdate>2023</risdate><volume>370</volume><spage>128529</spage><epage>128529</epage><pages>128529-128529</pages><artnum>128529</artnum><issn>0960-8524</issn><eissn>1873-2976</eissn><abstract>[Display omitted]
•A new idea for hydrocarbon production by co-torrefaction coupled with co-pyrolysis.•Hydrogen in oil-bath co-torrefied corncob increased from 5.21 wt% to 6.12 wt%.•Average activation energy of oil-bath co-torrefied corncob was 164.29 kJ/mol.•Oil-bath co-torrefaction residual was more suitable for bio-oil production.•Torrefaction temperature has the greatest effect on pyrolysis bio-oil composition.
Lignocellulosic biomass is a rich source of fixed renewable carbon and a promising alternative to fossil sources. However, low effective hydrogen to carbon ratio limits its applications. This work studied the influence of oil-bath co-torrefaction of corncob and waste cooking oil for co-pyrolysis. It was compared with dry torrefaction and hydrothermal wet torrefaction firstly. Residual of oil-bath co-torrefaction were the highest of 97.01 %. Oil-bath co-torrefaction could maximize hydrogen atoms retention in corncob, which has a positive significance for deoxygenation during pyrolysis. Oil-bath co-torrefaction could also reduce the average activation energy required for corncob decomposition, while it was increased with dry torrefaction. Oil-bath co-torrefaction coupled with co-pyrolysis was more suitable for hydrocarbon-rich bio-oil production. Oil-bath co-torrefaction temperature had the greatest influence on bio-oil composition. High pressure promoted formation of the CC double bond and degradation of lignin, which further promoted the formation of monocyclic aromatics in bio-oil.</abstract><cop>England</cop><pub>Elsevier Ltd</pub><pmid>36574887</pmid><doi>10.1016/j.biortech.2022.128529</doi><tpages>1</tpages></addata></record> |
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subjects | Bio-oil Biofuels Biomass Carbon Co-pyrolysis Co-torrefaction Cooking Corncob Hot Temperature Hydrogen Pyrolysis Waste cooking oil Zea mays |
title | Co-torrefaction of corncob and waste cooking oil coupled with fast co-pyrolysis for bio-oil production |
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