Mesostructured Metal Germanium Sulfide and Selenide Materials Based on the Tetrahedral [Ge4S10]4− and [Ge4Se10]4− Units: Surfactant Templated Three-Dimensional Disordered Frameworks Perforated with Worm Holes

The polymerization of [Ge4S10]4− and [Ge4Se10]4− unit clusters with the divalent metal ions Zn2+, Cd2+, Hg2+, Ni2+, and Co2+ in the presence of various surfactant cations leads to novel mesostructured phases. The surfactants are the quaternary ammonium salts C12H25NMe3Br, C14H29NMe3Br, C16H33NMe3Br,...

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Veröffentlicht in:	Journal of solid state chemistry 2000-06, Vol.152 (1), p.21-36
Hauptverfasser:	Wachhold, Michael, Kasthuri Rangan, K., Lei, Ming, Thorpe, M.F., Billinge, Simon J.L., Petkov, Valeri, Heising, Joy, Kanatzidis, Mercouri G.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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