Divergent synthesis of bis(indolyl)methanes via FeIII-catalysed regioselective dehydrogenative coupling reactions: a biomimetic approach to 6,6′-bis-(debromo)-gelliusine F

The divergent dehydrogenative coupling reactions of tryptamines with the catalysis of nontoxic FeIII salts in the presence of DDQ as the co-oxidant have been developed. Remarkably, the transformations feature a rapid and regioselective assembly of diverse 2,8′- and N1,8′-bis(indolyl) methane derivat...

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Veröffentlicht in:	Organic & biomolecular chemistry 2023-01, Vol.21 (3), p.639-643
Hauptverfasser:	Wu, Yan, Mou-De, Liu, Wang, Qing, Tian, Huan, Jin-Bao, Fan, Ying-Jun, Zhou, Ya-Jing, Wang, Deng, Xu
Format:	Artikel
Sprache:	eng
Schlagworte:	Biomimetics Catalysis Catalysts Chemical reactions Chemical synthesis Coupling Dehydrogenation Divergence Oxidants Oxidizing agents Regioselectivity Tryptamines
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