Low-energy ball-milling : Transformations of boron nitride powders. Crystallographic and chemical characterizations

BN powders (with and without water) which have undergone low-energyball-milling have been studied through X-ray diffraction,transmission electron microscopy, granulometry, electron energy loss(EELS) and IR spectroscopies. The main result is the formation of theorthorhombic and cubic high pressure ph...

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Veröffentlicht in:Journal of materials science 2000, Vol.35 (12), p.3003-3009
Hauptverfasser: GASGNIER, M, SZWARC, H, RONEZ, A
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SZWARC, H
RONEZ, A
description BN powders (with and without water) which have undergone low-energyball-milling have been studied through X-ray diffraction,transmission electron microscopy, granulometry, electron energy loss(EELS) and IR spectroscopies. The main result is the formation of theorthorhombic and cubic high pressure phases of BN. A “turbostratic”behaviour of hexagonal BN has also been observed. As expected, thegrain sizes decrease markedly. It is to be noticed that the presenceof water induces some chemical reactions which are revealed throughammonia-like and nitride compounds scents. However, according to EELSmeasurements, the main transformations are structural ones.
doi_str_mv 10.1023/A:1004735011914
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subjects Ball milling
Boron nitride
Chemical reactions
Chemistry
Colloidal state and disperse state
Crystallography
Electron energy loss spectroscopy
Energy dissipation
Energy transmission
Exact sciences and technology
General and physical chemistry
Materials science
Organic chemistry
Powders
Transformations
Transmission electron microscopy
title Low-energy ball-milling : Transformations of boron nitride powders. Crystallographic and chemical characterizations
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