Microenvironment Modulation of Metal–Organic Frameworks (MOFs) for Coordination Olefin Oligomerization and (co)Polymerization

The majority of commercial polyolefins are produced by coordination polymerization using early or late transition metal catalysts. Molecular catalysts containing these transition metals (Ti, Zr, Cr, Ni, and Fe, etc.) are loaded on supports for controlled polymerization behavior and polymer morpholog...

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