Fully Tin‐Coated Coinage Metal Ions: A Pincer‐Type Bis‐stannylene Ligand for Exclusive Tetrahedral Complexation

The synthesis of a novel bis‐stannylene pincer ligand and its complexation with coinage metals (CuI, AgI and AuI) are described. All coinage metal centres are in tetrahedral coordination environments in the solid state and are exclusively coordinated by four neutral SnII donors. 119Sn NMR provided i...

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Veröffentlicht in:	Chemistry : a European journal 2023-05, Vol.29 (27), p.e202203583-n/a
Hauptverfasser:	Krätschmer, Frederic, Sun, Xiaofei, Gillhuber, Sebastian, Kucher, Hannes, Franzke, Yannick J., Weigend, Florian, Roesky, Peter W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry coinage metals Complexation Coordination Density functional theory High temperature Ligands luminescence Metal ions Metals NMR Nuclear magnetic resonance Photoluminescence pincers Relativistic theory stannylene tetrahedra
Online-Zugang:	Volltext
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