Fully Tin‐Coated Coinage Metal Ions: A Pincer‐Type Bis‐stannylene Ligand for Exclusive Tetrahedral Complexation
The synthesis of a novel bis‐stannylene pincer ligand and its complexation with coinage metals (CuI, AgI and AuI) are described. All coinage metal centres are in tetrahedral coordination environments in the solid state and are exclusively coordinated by four neutral SnII donors. 119Sn NMR provided i...
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| Veröffentlicht in: | Chemistry : a European journal 2023-05, Vol.29 (27), p.e202203583-n/a |
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| creator | Krätschmer, Frederic Sun, Xiaofei Gillhuber, Sebastian Kucher, Hannes Franzke, Yannick J. Weigend, Florian Roesky, Peter W. |
| description | The synthesis of a novel bis‐stannylene pincer ligand and its complexation with coinage metals (CuI, AgI and AuI) are described. All coinage metal centres are in tetrahedral coordination environments in the solid state and are exclusively coordinated by four neutral SnII donors. 119Sn NMR provided information about the behaviour in solution. All of the isolated compounds have photoluminescent properties, and these were investigated at low and elevated temperatures. Compared to the free bis‐stannylene ligand, coordination to coinage metals led to an increase in the luminescence intensity. The new compounds were investigated in detail through all‐electron relativistic density functional theory (DFT) calculations.
Tin shines better with gold or silver: A luminescent pincer‐type bis‐stannylene ligand for exclusive tetrahedral coordination of the coinage metals was designed, and photoluminescence investigations as well as extensive quantum chemical calculations were carried out. |
| doi_str_mv | 10.1002/chem.202203583 |
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All coinage metal centres are in tetrahedral coordination environments in the solid state and are exclusively coordinated by four neutral SnII donors. 119Sn NMR provided information about the behaviour in solution. All of the isolated compounds have photoluminescent properties, and these were investigated at low and elevated temperatures. Compared to the free bis‐stannylene ligand, coordination to coinage metals led to an increase in the luminescence intensity. The new compounds were investigated in detail through all‐electron relativistic density functional theory (DFT) calculations.
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| subjects | Chemistry coinage metals Complexation Coordination Density functional theory High temperature Ligands luminescence Metal ions Metals NMR Nuclear magnetic resonance Photoluminescence pincers Relativistic theory stannylene tetrahedra |
| title | Fully Tin‐Coated Coinage Metal Ions: A Pincer‐Type Bis‐stannylene Ligand for Exclusive Tetrahedral Complexation |
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