Electrochemical polymerization of tetraphenylporphyrinatoruthenium(II) complexes with diaza compounds as axial ligands
The tetraphenylporphyrinatoruthenium(II) polymers bridged by the diaza compound (so called ‘shish kebab’-type polymers) were formed on the electrode by the two-electron oxidation of [Ru(tpp)L 2] (H 2tpp=5,10,15,20-tetraphenylporphyrin; L=4,4′-bipyridine, trans-1,2-bis(4-pyridyl)ethene, 1,2-bis(4-pyr...
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| Veröffentlicht in: | Electrochimica acta 2000-01, Vol.45 (18), p.3021-3028 |
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| container_title | Electrochimica acta |
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| creator | Saito, Miki Endo, Akira Shimizu, Kunio Satô, Gen P |
| description | The tetraphenylporphyrinatoruthenium(II) polymers bridged by the diaza compound (so called ‘shish kebab’-type polymers) were formed on the electrode by the two-electron oxidation of [Ru(tpp)L
2] (H
2tpp=5,10,15,20-tetraphenylporphyrin; L=4,4′-bipyridine,
trans-1,2-bis(4-pyridyl)ethene, 1,2-bis(4-pyridyl)ethine, 4,4′-azopyridine, 1,2-bis(4-pyridyl)disulfide)) in 0.1 mol dm
−3 (C
4H
9)
4N(ClO
4)CH
2Cl
2. This is the first example of electrochemical formation of shish kebab-type polymers, which until now have only been synthesized chemically. The polymer formed electrochemically was different from the polymer synthesized chemically. The former has the positively charged bridging ligands. The polymers showed reversible oxidation waves corresponding to the oxidation of Ru
II to Ru
III, and a reduction wave corresponding to the reduction of a positively charged bridging ligand. |
| doi_str_mv | 10.1016/S0013-4686(00)00381-9 |
| format | Article |
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2] (H
2tpp=5,10,15,20-tetraphenylporphyrin; L=4,4′-bipyridine,
trans-1,2-bis(4-pyridyl)ethene, 1,2-bis(4-pyridyl)ethine, 4,4′-azopyridine, 1,2-bis(4-pyridyl)disulfide)) in 0.1 mol dm
−3 (C
4H
9)
4N(ClO
4)CH
2Cl
2. This is the first example of electrochemical formation of shish kebab-type polymers, which until now have only been synthesized chemically. The polymer formed electrochemically was different from the polymer synthesized chemically. The former has the positively charged bridging ligands. The polymers showed reversible oxidation waves corresponding to the oxidation of Ru
II to Ru
III, and a reduction wave corresponding to the reduction of a positively charged bridging ligand.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/S0013-4686(00)00381-9</identifier><identifier>CODEN: ELCAAV</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Diaza compounds ; Electrooxidative polymerization ; Exact sciences and technology ; Metal porphyrin polymer ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Porphyrin ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Ruthenium</subject><ispartof>Electrochimica acta, 2000-01, Vol.45 (18), p.3021-3028</ispartof><rights>2000 Elsevier Science Ltd</rights><rights>2000 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-34bceb7b6c3b8e61c7d1e1203225333768115c8fe65fef40a125812bbde2541a3</citedby><cites>FETCH-LOGICAL-c367t-34bceb7b6c3b8e61c7d1e1203225333768115c8fe65fef40a125812bbde2541a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0013468600003819$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>309,310,314,776,780,785,786,3537,23909,23910,25118,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1394562$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Saito, Miki</creatorcontrib><creatorcontrib>Endo, Akira</creatorcontrib><creatorcontrib>Shimizu, Kunio</creatorcontrib><creatorcontrib>Satô, Gen P</creatorcontrib><title>Electrochemical polymerization of tetraphenylporphyrinatoruthenium(II) complexes with diaza compounds as axial ligands</title><title>Electrochimica acta</title><description>The tetraphenylporphyrinatoruthenium(II) polymers bridged by the diaza compound (so called ‘shish kebab’-type polymers) were formed on the electrode by the two-electron oxidation of [Ru(tpp)L
2] (H
2tpp=5,10,15,20-tetraphenylporphyrin; L=4,4′-bipyridine,
trans-1,2-bis(4-pyridyl)ethene, 1,2-bis(4-pyridyl)ethine, 4,4′-azopyridine, 1,2-bis(4-pyridyl)disulfide)) in 0.1 mol dm
−3 (C
4H
9)
4N(ClO
4)CH
2Cl
2. This is the first example of electrochemical formation of shish kebab-type polymers, which until now have only been synthesized chemically. The polymer formed electrochemically was different from the polymer synthesized chemically. The former has the positively charged bridging ligands. The polymers showed reversible oxidation waves corresponding to the oxidation of Ru
II to Ru
III, and a reduction wave corresponding to the reduction of a positively charged bridging ligand.</description><subject>Applied sciences</subject><subject>Diaza compounds</subject><subject>Electrooxidative polymerization</subject><subject>Exact sciences and technology</subject><subject>Metal porphyrin polymer</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Porphyrin</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Ruthenium</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNqFkMFq3DAQhkVJoZu0j1DwIYTk4HYkWZL3FEJI24VAD23PQpbHXRXZciQ5yebpq-yG5lgYGPj5Zob5CPlI4RMFKj__AKC8bmQrzwEuAHhL6_UbsqKt4jVvxfqIrP4h78hxSn8AQEkFK3J_49HmGOwWR2eNr-bgdyNG92SyC1MVhipjjmbe4rTzc4jzdhfdZHKISy6ZW8bzzeaismGcPT5iqh5c3la9M09mH4Zl6lNlSj26st6736YE78nbwfiEH176Cfn15ebn9bf69vvXzfXVbW25VLnmTWexU520vGtRUqt6ipQBZ0xwzpVsKRW2HVCKAYcGDGWipazremSioYafkLPD3jmGuwVT1qNLFr03E4YlaaaEUILRAooDaGNIKeKg5-hGE3eagn62rPeW9bNCDaD3lvW6zJ2-HDCp6BuimaxLr8N83QjJCnZ5wLA8e-8w6mQdThZ7F4t_3Qf3n0N_AerglCY</recordid><startdate>20000101</startdate><enddate>20000101</enddate><creator>Saito, Miki</creator><creator>Endo, Akira</creator><creator>Shimizu, Kunio</creator><creator>Satô, Gen P</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20000101</creationdate><title>Electrochemical polymerization of tetraphenylporphyrinatoruthenium(II) complexes with diaza compounds as axial ligands</title><author>Saito, Miki ; Endo, Akira ; Shimizu, Kunio ; Satô, Gen P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-34bceb7b6c3b8e61c7d1e1203225333768115c8fe65fef40a125812bbde2541a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>Applied sciences</topic><topic>Diaza compounds</topic><topic>Electrooxidative polymerization</topic><topic>Exact sciences and technology</topic><topic>Metal porphyrin polymer</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Porphyrin</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Ruthenium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Saito, Miki</creatorcontrib><creatorcontrib>Endo, Akira</creatorcontrib><creatorcontrib>Shimizu, Kunio</creatorcontrib><creatorcontrib>Satô, Gen P</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Saito, Miki</au><au>Endo, Akira</au><au>Shimizu, Kunio</au><au>Satô, Gen P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical polymerization of tetraphenylporphyrinatoruthenium(II) complexes with diaza compounds as axial ligands</atitle><jtitle>Electrochimica acta</jtitle><date>2000-01-01</date><risdate>2000</risdate><volume>45</volume><issue>18</issue><spage>3021</spage><epage>3028</epage><pages>3021-3028</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>The tetraphenylporphyrinatoruthenium(II) polymers bridged by the diaza compound (so called ‘shish kebab’-type polymers) were formed on the electrode by the two-electron oxidation of [Ru(tpp)L
2] (H
2tpp=5,10,15,20-tetraphenylporphyrin; L=4,4′-bipyridine,
trans-1,2-bis(4-pyridyl)ethene, 1,2-bis(4-pyridyl)ethine, 4,4′-azopyridine, 1,2-bis(4-pyridyl)disulfide)) in 0.1 mol dm
−3 (C
4H
9)
4N(ClO
4)CH
2Cl
2. This is the first example of electrochemical formation of shish kebab-type polymers, which until now have only been synthesized chemically. The polymer formed electrochemically was different from the polymer synthesized chemically. The former has the positively charged bridging ligands. The polymers showed reversible oxidation waves corresponding to the oxidation of Ru
II to Ru
III, and a reduction wave corresponding to the reduction of a positively charged bridging ligand.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0013-4686(00)00381-9</doi><tpages>8</tpages></addata></record> |
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| subjects | Applied sciences Diaza compounds Electrooxidative polymerization Exact sciences and technology Metal porphyrin polymer Organic polymers Physicochemistry of polymers Polymerization Porphyrin Preparation, kinetics, thermodynamics, mechanism and catalysts Ruthenium |
| title | Electrochemical polymerization of tetraphenylporphyrinatoruthenium(II) complexes with diaza compounds as axial ligands |
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