Hydrogen/nitrogen dioxide kinetics - Derived data for the reaction H2 + NO2 = HONO + H at 833 K

Hydrogen/nitrogen dioxide kinetics - Derived data for the reaction H2 + NO2 = HONO + H at 833 K

New experimental data are reported for the reaction of H2 with NO2 at temperatures near 833 K and pressures of 1.2-5.0 atm. Numerical predictions from a previously published reaction mechanism are in good agreement with the measured species profiles at 833 K only when the recommended rate constant f...

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Veröffentlicht in:Combustion and flame 2000-03, Vol.120 (4), p.589-594
Hauptverfasser: Mueller, Mark A, Gatto, Jeffrey L, Yetter, Richard A, Dryer, Frederick L
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container_title Combustion and flame
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creator Mueller, Mark A
Gatto, Jeffrey L
Yetter, Richard A
Dryer, Frederick L
description New experimental data are reported for the reaction of H2 with NO2 at temperatures near 833 K and pressures of 1.2-5.0 atm. Numerical predictions from a previously published reaction mechanism are in good agreement with the measured species profiles at 833 K only when the recommended rate constant for the reaction is reduced by a factor of 30. The rate data derived here are in good agreement with the theoretical expression of Park et al. (1998). Steady state analyses of a simple five-step mechanism are used to develop an analytical expression for NO2 consumption that predicts well the high-pressure data. (AIAA)
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title Hydrogen/nitrogen dioxide kinetics - Derived data for the reaction H2 + NO2 = HONO + H at 833 K
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