Grain growth of nanocrystalline Fe–Al alloys produced by cryomilling in liquid argon and nitrogen

Cryomilling of Fe–10 wt.%Al powders in liquid argon as well as in liquid nitrogen resulted in nanocrystalline structures which were thermally stable at least up to 1223 K, or 67% of the melting temperature of Fe. In contrast, cryomilling of elemental Fe resulted in a nanocrystalline structure which...

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Veröffentlicht in:Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 1998-10, Vol.255 (1), p.124-132
Hauptverfasser: Huang, B., Perez, R.J., Lavernia, E.J.
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container_title Materials science & engineering. A, Structural materials : properties, microstructure and processing
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creator Huang, B.
Perez, R.J.
Lavernia, E.J.
description Cryomilling of Fe–10 wt.%Al powders in liquid argon as well as in liquid nitrogen resulted in nanocrystalline structures which were thermally stable at least up to 1223 K, or 67% of the melting temperature of Fe. In contrast, cryomilling of elemental Fe resulted in a nanocrystalline structure which grew to a sub-micron scale following annealing at 1223 K. The enhanced thermal stability of the cryomilled Fe–10 wt.%Al powders in liquid argon was attributed to the formation of γ-Al 2O 3 due to the moisture condensation. The thermal stability of the Fe–10 wt.%Al powders milled in liquid nitrogen was attributed to the formation of oxynitrides, or γ-Al 2O 3 and AlN particles during cryomilling in liquid nitrogen. The formation of Fe 3O 4 particles did not result in enhanced thermal stability. The presence of Al is essential in achieving thermal stability of nanocrystalline structures in cryomilled Fe powders.
doi_str_mv 10.1016/S0921-5093(98)00765-5
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subjects Applied sciences
Cryomilling
Exact sciences and technology
Fe–Al alloys
Metal powders
Metals. Metallurgy
Powder metallurgy. Composite materials
Production techniques
Thermal stability
title Grain growth of nanocrystalline Fe–Al alloys produced by cryomilling in liquid argon and nitrogen
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