Reductive Alkenylation of Ketimines via Hydride Transfer from Aldehydes

The first direct N-heterocyclic carbene (NHC)-catalyzed preparation of allylic amines bearing a quaternary center (α-tertiary amine) from isatin-derived ketimines in the presence of vinyl selenones and aldehydes is reported. This multicomponent reaction is expected to proceed via unprecedented in si...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of organic chemistry 2023-01, Vol.88 (1), p.632-639
Hauptverfasser:	Azaz, Tazeen, Mourya, Hemlata, Singh, Vikram, Ram, Bali, Tiwari, Bhoopendra
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Amines Catalysis Imines Isatin Molecular Structure
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!