CpRh(III)‐Catalyzed C−H Arylation of Ferrocenethionamides with Aryl Boronic Acids for the Synthesis of Aryl‐Ferrocenes

We developed a Cp*Rh(III)‐catalyzed C−H arylation of ferrocenethionamides with arylboronic acids for the synthesis of aryl‐ferrocenes under mild and base‐free conditions, using Ag2CO3 as oxidant. The reaction results in high yields and excellent regioselectivity accommodating a broad scope of substr...

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Veröffentlicht in:	Chemistry, an Asian journal an Asian journal, 2023-01, Vol.18 (2), p.e202201180-n/a
Hauptverfasser:	Wang, Yingxin, Ban, Yan, Wang, Bosen, Li, Hao, Gong, Chengwei, Wang, Yan, Wang, Fuqiang, Li, Dianjun, Yang, Jinhui
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds aryl-ferrocene products base-free conditions Boronic Acids - chemistry Catalysis Chemistry CpRh(III)-catalyzed C−H arylation Ferrocenes ferrocenethionamides Functional groups Metallocenes Oxidizing agents Regioselectivity Substrates
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