CpRh(III)‐Catalyzed C−H Arylation of Ferrocenethionamides with Aryl Boronic Acids for the Synthesis of Aryl‐Ferrocenes
We developed a Cp*Rh(III)‐catalyzed C−H arylation of ferrocenethionamides with arylboronic acids for the synthesis of aryl‐ferrocenes under mild and base‐free conditions, using Ag2CO3 as oxidant. The reaction results in high yields and excellent regioselectivity accommodating a broad scope of substr...
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| Veröffentlicht in: | Chemistry, an Asian journal an Asian journal, 2023-01, Vol.18 (2), p.e202201180-n/a |
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| container_title | Chemistry, an Asian journal |
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| creator | Wang, Yingxin Ban, Yan Wang, Bosen Li, Hao Gong, Chengwei Wang, Yan Wang, Fuqiang Li, Dianjun Yang, Jinhui |
| description | We developed a Cp*Rh(III)‐catalyzed C−H arylation of ferrocenethionamides with arylboronic acids for the synthesis of aryl‐ferrocenes under mild and base‐free conditions, using Ag2CO3 as oxidant. The reaction results in high yields and excellent regioselectivity accommodating a broad scope of substrate range and functional group compatibility, and provides an alternative protocol for the generation of highly functionalized aryl‐ferrocene compounds.
A Cp*Rh(III)‐catalyzed C‐H arylation of ferrocenethionamides with arylboronic acids for the synthesis of aryl‐ferrocenes under mild and base‐free conditions is reported, using Ag2CO3 as oxidant. The reaction results in high yields and excellent regioselectivity accommodating a broad scope of substrate range and functional group compatibility, and provides an alternative protocol for the generation of highly functionalized aryl‐ferrocene compounds. |
| doi_str_mv | 10.1002/asia.202201180 |
| format | Article |
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A Cp*Rh(III)‐catalyzed C‐H arylation of ferrocenethionamides with arylboronic acids for the synthesis of aryl‐ferrocenes under mild and base‐free conditions is reported, using Ag2CO3 as oxidant. The reaction results in high yields and excellent regioselectivity accommodating a broad scope of substrate range and functional group compatibility, and provides an alternative protocol for the generation of highly functionalized aryl‐ferrocene compounds.</description><identifier>ISSN: 1861-4728</identifier><identifier>EISSN: 1861-471X</identifier><identifier>DOI: 10.1002/asia.202201180</identifier><identifier>PMID: 36495085</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Aromatic compounds ; aryl-ferrocene products ; base-free conditions ; Boronic Acids - chemistry ; Catalysis ; Chemistry ; CpRh(III)-catalyzed ; C−H arylation ; Ferrocenes ; ferrocenethionamides ; Functional groups ; Metallocenes ; Oxidizing agents ; Regioselectivity ; Substrates</subject><ispartof>Chemistry, an Asian journal, 2023-01, Vol.18 (2), p.e202201180-n/a</ispartof><rights>2022 Wiley‐VCH GmbH</rights><rights>2022 Wiley-VCH GmbH.</rights><rights>2023 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2580-e89a56f286b490faafaf455e186370e870be14705cacbbfabb97a24f0a4d8d3d3</cites><orcidid>0000-0003-1639-8335 ; 0000-0003-2653-1611 ; 0000-0002-3980-7886</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fasia.202201180$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fasia.202201180$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27929,27930,45579,45580</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36495085$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Yingxin</creatorcontrib><creatorcontrib>Ban, Yan</creatorcontrib><creatorcontrib>Wang, Bosen</creatorcontrib><creatorcontrib>Li, Hao</creatorcontrib><creatorcontrib>Gong, Chengwei</creatorcontrib><creatorcontrib>Wang, Yan</creatorcontrib><creatorcontrib>Wang, Fuqiang</creatorcontrib><creatorcontrib>Li, Dianjun</creatorcontrib><creatorcontrib>Yang, Jinhui</creatorcontrib><title>CpRh(III)‐Catalyzed C−H Arylation of Ferrocenethionamides with Aryl Boronic Acids for the Synthesis of Aryl‐Ferrocenes</title><title>Chemistry, an Asian journal</title><addtitle>Chem Asian J</addtitle><description>We developed a Cp*Rh(III)‐catalyzed C−H arylation of ferrocenethionamides with arylboronic acids for the synthesis of aryl‐ferrocenes under mild and base‐free conditions, using Ag2CO3 as oxidant. The reaction results in high yields and excellent regioselectivity accommodating a broad scope of substrate range and functional group compatibility, and provides an alternative protocol for the generation of highly functionalized aryl‐ferrocene compounds.
A Cp*Rh(III)‐catalyzed C‐H arylation of ferrocenethionamides with arylboronic acids for the synthesis of aryl‐ferrocenes under mild and base‐free conditions is reported, using Ag2CO3 as oxidant. The reaction results in high yields and excellent regioselectivity accommodating a broad scope of substrate range and functional group compatibility, and provides an alternative protocol for the generation of highly functionalized aryl‐ferrocene compounds.</description><subject>Aromatic compounds</subject><subject>aryl-ferrocene products</subject><subject>base-free conditions</subject><subject>Boronic Acids - chemistry</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>CpRh(III)-catalyzed</subject><subject>C−H arylation</subject><subject>Ferrocenes</subject><subject>ferrocenethionamides</subject><subject>Functional groups</subject><subject>Metallocenes</subject><subject>Oxidizing agents</subject><subject>Regioselectivity</subject><subject>Substrates</subject><issn>1861-4728</issn><issn>1861-471X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkTFr3DAYhkVJadK0a8ciyJIMd_kkW5Y8OqZJDIFC0kI3I9ufOAWfdZV8BIcMHTOW_MT8kup66RW6dHqFePTo-3gJ-cBgzgD4qQ5WzzlwDowpeEUOmMrYLJXs297uzNU-eRvCLYDgkKs3ZD_J0lyAEgfkoVxdL46rqjp5_vGz1KPup3vsaPn8-HRJCz_1erRuoM7Qc_TetTjguIg3emk7DPTOjovfGD1z3g22pUVru0CN83RcIL2ZhhjBho1hw8VfdqLwjrw2ug_4_iUPydfzT1_Ky9nV54uqLK5mLRcKZqhyLTLDVdakORitjTapEBjXSySgktAgSyWIVrdNY3TT5FLz1IBOO9UlXXJIjrfelXff1xjGemlDi32vB3TrUHMpkoQxkWcRPfoHvXVrP8TpIiUTKXguk0jNt1TrXQgeTb3ydqn9VDOoN73Um17qXS_xwccX7bpZYrfD_xQRgXwL3Nkep__o6uKmKv7KfwH5oZ0e</recordid><startdate>20230117</startdate><enddate>20230117</enddate><creator>Wang, Yingxin</creator><creator>Ban, Yan</creator><creator>Wang, Bosen</creator><creator>Li, Hao</creator><creator>Gong, Chengwei</creator><creator>Wang, Yan</creator><creator>Wang, Fuqiang</creator><creator>Li, Dianjun</creator><creator>Yang, Jinhui</creator><general>Wiley Subscription Services, Inc</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-1639-8335</orcidid><orcidid>https://orcid.org/0000-0003-2653-1611</orcidid><orcidid>https://orcid.org/0000-0002-3980-7886</orcidid></search><sort><creationdate>20230117</creationdate><title>CpRh(III)‐Catalyzed C−H Arylation of Ferrocenethionamides with Aryl Boronic Acids for the Synthesis of Aryl‐Ferrocenes</title><author>Wang, Yingxin ; Ban, Yan ; Wang, Bosen ; Li, Hao ; Gong, Chengwei ; Wang, Yan ; Wang, Fuqiang ; Li, Dianjun ; Yang, Jinhui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2580-e89a56f286b490faafaf455e186370e870be14705cacbbfabb97a24f0a4d8d3d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aromatic compounds</topic><topic>aryl-ferrocene products</topic><topic>base-free conditions</topic><topic>Boronic Acids - chemistry</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>CpRh(III)-catalyzed</topic><topic>C−H arylation</topic><topic>Ferrocenes</topic><topic>ferrocenethionamides</topic><topic>Functional groups</topic><topic>Metallocenes</topic><topic>Oxidizing agents</topic><topic>Regioselectivity</topic><topic>Substrates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Yingxin</creatorcontrib><creatorcontrib>Ban, Yan</creatorcontrib><creatorcontrib>Wang, Bosen</creatorcontrib><creatorcontrib>Li, Hao</creatorcontrib><creatorcontrib>Gong, Chengwei</creatorcontrib><creatorcontrib>Wang, Yan</creatorcontrib><creatorcontrib>Wang, Fuqiang</creatorcontrib><creatorcontrib>Li, Dianjun</creatorcontrib><creatorcontrib>Yang, Jinhui</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry, an Asian journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Yingxin</au><au>Ban, Yan</au><au>Wang, Bosen</au><au>Li, Hao</au><au>Gong, Chengwei</au><au>Wang, Yan</au><au>Wang, Fuqiang</au><au>Li, Dianjun</au><au>Yang, Jinhui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>CpRh(III)‐Catalyzed C−H Arylation of Ferrocenethionamides with Aryl Boronic Acids for the Synthesis of Aryl‐Ferrocenes</atitle><jtitle>Chemistry, an Asian journal</jtitle><addtitle>Chem Asian J</addtitle><date>2023-01-17</date><risdate>2023</risdate><volume>18</volume><issue>2</issue><spage>e202201180</spage><epage>n/a</epage><pages>e202201180-n/a</pages><issn>1861-4728</issn><eissn>1861-471X</eissn><abstract>We developed a Cp*Rh(III)‐catalyzed C−H arylation of ferrocenethionamides with arylboronic acids for the synthesis of aryl‐ferrocenes under mild and base‐free conditions, using Ag2CO3 as oxidant. The reaction results in high yields and excellent regioselectivity accommodating a broad scope of substrate range and functional group compatibility, and provides an alternative protocol for the generation of highly functionalized aryl‐ferrocene compounds.
A Cp*Rh(III)‐catalyzed C‐H arylation of ferrocenethionamides with arylboronic acids for the synthesis of aryl‐ferrocenes under mild and base‐free conditions is reported, using Ag2CO3 as oxidant. The reaction results in high yields and excellent regioselectivity accommodating a broad scope of substrate range and functional group compatibility, and provides an alternative protocol for the generation of highly functionalized aryl‐ferrocene compounds.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>36495085</pmid><doi>10.1002/asia.202201180</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-1639-8335</orcidid><orcidid>https://orcid.org/0000-0003-2653-1611</orcidid><orcidid>https://orcid.org/0000-0002-3980-7886</orcidid></addata></record> |
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| subjects | Aromatic compounds aryl-ferrocene products base-free conditions Boronic Acids - chemistry Catalysis Chemistry CpRh(III)-catalyzed C−H arylation Ferrocenes ferrocenethionamides Functional groups Metallocenes Oxidizing agents Regioselectivity Substrates |
| title | CpRh(III)‐Catalyzed C−H Arylation of Ferrocenethionamides with Aryl Boronic Acids for the Synthesis of Aryl‐Ferrocenes |
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