Effect of silane-based filler surface treatment formulation on the interfacial properties of impact modified polypropylene/magnesium hydroxide composites
Magnesium hydroxide (Mg(OH) 2) flame retardant filler has been treated with combinations of vinyltriethoxysilane (VS), dicumyl peroxide (DCP) and trimethylolpropane triacrylate (TMPTA) and melt blended to V f=0.14 and 0.41, (30% w/w and 65% w/w) with an impact modified polypropylene matrix. The VS/D...
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| Veröffentlicht in: | Composites. Part A, Applied science and manufacturing Applied science and manufacturing, 1998, Vol.29 (9), p.1313-1318 |
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| container_title | Composites. Part A, Applied science and manufacturing |
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| creator | Liauw, C.M Lees, G.C Hurst, S.J Rothon, R.N Ali, S |
| description | Magnesium hydroxide (Mg(OH)
2) flame retardant filler has been treated with combinations of vinyltriethoxysilane (VS), dicumyl peroxide (DCP) and trimethylolpropane triacrylate (TMPTA) and melt blended to
V
f=0.14 and 0.41, (30% w/w and 65% w/w) with an impact modified polypropylene matrix. The VS/DCP combination afforded the best balance of strength and toughness at
V
f=0.41. The superiority of this system was found to be due to encapsulation of the filler particles by the crosslinked elastomeric phase of the matrix which was confirmed by secant modulus measurements and low temperature fractography. The data obtained from this study form the basis of a proposed mechanism for this encapsulation effect. |
| doi_str_mv | 10.1016/S1359-835X(97)00132-2 |
| format | Article |
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2) flame retardant filler has been treated with combinations of vinyltriethoxysilane (VS), dicumyl peroxide (DCP) and trimethylolpropane triacrylate (TMPTA) and melt blended to
V
f=0.14 and 0.41, (30% w/w and 65% w/w) with an impact modified polypropylene matrix. The VS/DCP combination afforded the best balance of strength and toughness at
V
f=0.41. The superiority of this system was found to be due to encapsulation of the filler particles by the crosslinked elastomeric phase of the matrix which was confirmed by secant modulus measurements and low temperature fractography. The data obtained from this study form the basis of a proposed mechanism for this encapsulation effect.</description><identifier>ISSN: 1359-835X</identifier><identifier>EISSN: 1878-5840</identifier><identifier>DOI: 10.1016/S1359-835X(97)00132-2</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Composites ; Exact sciences and technology ; Forms of application and semi-finished materials ; magnesium hydroxide ; Polymer industry, paints, wood ; polypropylene ; silane ; Technology of polymers</subject><ispartof>Composites. Part A, Applied science and manufacturing, 1998, Vol.29 (9), p.1313-1318</ispartof><rights>1998 Elsevier Science Ltd</rights><rights>1999 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-5b22085805f94e63303ae84448e83bdc48d9e9864d3e49efe5dfd20c975cae833</citedby><cites>FETCH-LOGICAL-c367t-5b22085805f94e63303ae84448e83bdc48d9e9864d3e49efe5dfd20c975cae833</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S1359-835X(97)00132-2$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>309,310,314,780,784,789,790,3550,4024,4050,4051,23930,23931,25140,27923,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1613385$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Liauw, C.M</creatorcontrib><creatorcontrib>Lees, G.C</creatorcontrib><creatorcontrib>Hurst, S.J</creatorcontrib><creatorcontrib>Rothon, R.N</creatorcontrib><creatorcontrib>Ali, S</creatorcontrib><title>Effect of silane-based filler surface treatment formulation on the interfacial properties of impact modified polypropylene/magnesium hydroxide composites</title><title>Composites. Part A, Applied science and manufacturing</title><description>Magnesium hydroxide (Mg(OH)
2) flame retardant filler has been treated with combinations of vinyltriethoxysilane (VS), dicumyl peroxide (DCP) and trimethylolpropane triacrylate (TMPTA) and melt blended to
V
f=0.14 and 0.41, (30% w/w and 65% w/w) with an impact modified polypropylene matrix. The VS/DCP combination afforded the best balance of strength and toughness at
V
f=0.41. The superiority of this system was found to be due to encapsulation of the filler particles by the crosslinked elastomeric phase of the matrix which was confirmed by secant modulus measurements and low temperature fractography. The data obtained from this study form the basis of a proposed mechanism for this encapsulation effect.</description><subject>Applied sciences</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>magnesium hydroxide</subject><subject>Polymer industry, paints, wood</subject><subject>polypropylene</subject><subject>silane</subject><subject>Technology of polymers</subject><issn>1359-835X</issn><issn>1878-5840</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkcuKFTEQhhtRcBx9BCELEV20k3Q63clKZBgvMOBCBXchJ6k4JUmnTdLieRTf1vScEZdCQdXiq78uf9c9ZfQVo2y6-MS4UL3k4usLNb-klPGhH-51Z0zOshdypPdb_Rd52D0q5TullHPFzrrfV96DrSR5UjCYBfqDKeCIxxAgk7JlbyyQmsHUCEslPuW4BVMxLaRFvQGCS4UdQxPImtMKuSKUXRLjapp4TA49NtU1heNOHAMscBHNtwUKbpHcHF1Ov9ABsSmuqWCF8rh74E0o8OQun3df3l59vnzfX3989-HyzXVv-TTXXhyGgUohqfBqhIlzyg3IcRwlSH5wdpROgZLT6DiMCjwI591ArZqFbSDn593zk25b7McGpeqIxULYn5G2oodZDHRmQwPFCbQ5lZLB6zVjNPmoGdW7EfrWCL1_WatZ3xqh975ndwNMsSb4bBaL5V_zxDiXomGvTxi0Y38iZF0swmLBYW4OaZfwP4P-AMmIoic</recordid><startdate>1998</startdate><enddate>1998</enddate><creator>Liauw, C.M</creator><creator>Lees, G.C</creator><creator>Hurst, S.J</creator><creator>Rothon, R.N</creator><creator>Ali, S</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>1998</creationdate><title>Effect of silane-based filler surface treatment formulation on the interfacial properties of impact modified polypropylene/magnesium hydroxide composites</title><author>Liauw, C.M ; Lees, G.C ; Hurst, S.J ; Rothon, R.N ; Ali, S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-5b22085805f94e63303ae84448e83bdc48d9e9864d3e49efe5dfd20c975cae833</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Applied sciences</topic><topic>Composites</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>magnesium hydroxide</topic><topic>Polymer industry, paints, wood</topic><topic>polypropylene</topic><topic>silane</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liauw, C.M</creatorcontrib><creatorcontrib>Lees, G.C</creatorcontrib><creatorcontrib>Hurst, S.J</creatorcontrib><creatorcontrib>Rothon, R.N</creatorcontrib><creatorcontrib>Ali, S</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Composites. Part A, Applied science and manufacturing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liauw, C.M</au><au>Lees, G.C</au><au>Hurst, S.J</au><au>Rothon, R.N</au><au>Ali, S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of silane-based filler surface treatment formulation on the interfacial properties of impact modified polypropylene/magnesium hydroxide composites</atitle><jtitle>Composites. Part A, Applied science and manufacturing</jtitle><date>1998</date><risdate>1998</risdate><volume>29</volume><issue>9</issue><spage>1313</spage><epage>1318</epage><pages>1313-1318</pages><issn>1359-835X</issn><eissn>1878-5840</eissn><abstract>Magnesium hydroxide (Mg(OH)
2) flame retardant filler has been treated with combinations of vinyltriethoxysilane (VS), dicumyl peroxide (DCP) and trimethylolpropane triacrylate (TMPTA) and melt blended to
V
f=0.14 and 0.41, (30% w/w and 65% w/w) with an impact modified polypropylene matrix. The VS/DCP combination afforded the best balance of strength and toughness at
V
f=0.41. The superiority of this system was found to be due to encapsulation of the filler particles by the crosslinked elastomeric phase of the matrix which was confirmed by secant modulus measurements and low temperature fractography. The data obtained from this study form the basis of a proposed mechanism for this encapsulation effect.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S1359-835X(97)00132-2</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-835X |
| ispartof | Composites. Part A, Applied science and manufacturing, 1998, Vol.29 (9), p.1313-1318 |
| issn | 1359-835X 1878-5840 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_27520712 |
| source | Elsevier ScienceDirect Journals Complete |
| subjects | Applied sciences Composites Exact sciences and technology Forms of application and semi-finished materials magnesium hydroxide Polymer industry, paints, wood polypropylene silane Technology of polymers |
| title | Effect of silane-based filler surface treatment formulation on the interfacial properties of impact modified polypropylene/magnesium hydroxide composites |
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