Cathodic polarization of Al–Sn alloy in sodium chloride solution
The results presented in this paper were obtained with two Al–Sn binary alloys (0.02 and 0.4 wt% Sn) which had been prepared on super pure (99.999%) Al base. A study of behaviour of these alloys at cathodic polarization in 2 M NaCl solution by means of electrochemical methods complemented by SEM and...
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Veröffentlicht in: | Electrochimica acta 1998-01, Vol.43 (21), p.3241-3255 |
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container_title | Electrochimica acta |
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creator | KLISKIC, M RADOSEVIC, J GUDIC, S SMITH, M |
description | The results presented in this paper were obtained with two Al–Sn binary alloys (0.02 and 0.4
wt% Sn) which had been prepared on super pure (99.999%) Al base. A study of behaviour of these alloys at cathodic polarization in 2
M NaCl solution by means of electrochemical methods complemented by SEM and EDAX analysis provided an insight into the effect of addition of tin on the electrochemical behaviour of aluminium. It has been observed that a low tin content causes aluminium to behave hyperactively at high negative potential values, which leads to crevice formation and conditions favourable for further dissolution. The result of the change of potential in the negative direction with the alloy containing 0.4
wt% tin is superactivation of aluminium as consequence of de-filming processes. |
doi_str_mv | 10.1016/S0013-4686(98)00001-2 |
format | Article |
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wt% Sn) which had been prepared on super pure (99.999%) Al base. A study of behaviour of these alloys at cathodic polarization in 2
M NaCl solution by means of electrochemical methods complemented by SEM and EDAX analysis provided an insight into the effect of addition of tin on the electrochemical behaviour of aluminium. It has been observed that a low tin content causes aluminium to behave hyperactively at high negative potential values, which leads to crevice formation and conditions favourable for further dissolution. The result of the change of potential in the negative direction with the alloy containing 0.4
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wt% Sn) which had been prepared on super pure (99.999%) Al base. A study of behaviour of these alloys at cathodic polarization in 2
M NaCl solution by means of electrochemical methods complemented by SEM and EDAX analysis provided an insight into the effect of addition of tin on the electrochemical behaviour of aluminium. It has been observed that a low tin content causes aluminium to behave hyperactively at high negative potential values, which leads to crevice formation and conditions favourable for further dissolution. The result of the change of potential in the negative direction with the alloy containing 0.4
wt% tin is superactivation of aluminium as consequence of de-filming processes.</description><subject>Al–Sn alloy</subject><subject>Applied sciences</subject><subject>cathodic polarization</subject><subject>Corrosion</subject><subject>Corrosion environments</subject><subject>Exact sciences and technology</subject><subject>high purity aluminium</subject><subject>Metals. Metallurgy</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkM9KAzEQh4MoWKuPIOxBRA-rySabZE9Si_-g4KF6Dml2QiPppia7Qj35Dr6hT-K2lV6dyzDw_WaYD6FTgq8IJvx6ijGhOeOSX1TyEvdF8mIPDYgUNKeyrPbRYIccoqOU3npGcIEH6Has23moncmWwevoPnXrQpMFm438z9f3tMm092GVuSZLPdYtMjP3Iboa-tl3a_gYHVjtE5z89SF6vb97GT_mk-eHp_FokhvKRZsXgkpWlcAZLwsxA2E4lAyXmlqusaXc1qyora2kFtIyYSqgnNGZlJLTSmA6ROfbvcsY3jtIrVq4ZMB73UDokioEk4xw0YPlFjQxpBTBqmV0Cx1XimC1NqY2xtRah6qk2hhTRZ87-zugk9HeRt0Yl3bhggpRyjV2s8Wgf_bDQVTJOGgM1C6CaVUd3D-HfgH1ZH9W</recordid><startdate>19980101</startdate><enddate>19980101</enddate><creator>KLISKIC, M</creator><creator>RADOSEVIC, J</creator><creator>GUDIC, S</creator><creator>SMITH, M</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>19980101</creationdate><title>Cathodic polarization of Al–Sn alloy in sodium chloride solution</title><author>KLISKIC, M ; RADOSEVIC, J ; GUDIC, S ; SMITH, M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-2738495e646527be7c6e5405a3f6a0f36fd42dff98a78f47c9e3643b888639703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Al–Sn alloy</topic><topic>Applied sciences</topic><topic>cathodic polarization</topic><topic>Corrosion</topic><topic>Corrosion environments</topic><topic>Exact sciences and technology</topic><topic>high purity aluminium</topic><topic>Metals. Metallurgy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>KLISKIC, M</creatorcontrib><creatorcontrib>RADOSEVIC, J</creatorcontrib><creatorcontrib>GUDIC, S</creatorcontrib><creatorcontrib>SMITH, M</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>KLISKIC, M</au><au>RADOSEVIC, J</au><au>GUDIC, S</au><au>SMITH, M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cathodic polarization of Al–Sn alloy in sodium chloride solution</atitle><jtitle>Electrochimica acta</jtitle><date>1998-01-01</date><risdate>1998</risdate><volume>43</volume><issue>21</issue><spage>3241</spage><epage>3255</epage><pages>3241-3255</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>The results presented in this paper were obtained with two Al–Sn binary alloys (0.02 and 0.4
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M NaCl solution by means of electrochemical methods complemented by SEM and EDAX analysis provided an insight into the effect of addition of tin on the electrochemical behaviour of aluminium. It has been observed that a low tin content causes aluminium to behave hyperactively at high negative potential values, which leads to crevice formation and conditions favourable for further dissolution. The result of the change of potential in the negative direction with the alloy containing 0.4
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source | ScienceDirect Journals (5 years ago - present) |
subjects | Al–Sn alloy Applied sciences cathodic polarization Corrosion Corrosion environments Exact sciences and technology high purity aluminium Metals. Metallurgy |
title | Cathodic polarization of Al–Sn alloy in sodium chloride solution |
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