Coordination compound films of 1-phenyl-5-mercaptotetrazole on copper surface
The chemical nature of the coordination compound film formed by reacting PMTA (1-phenyl-5-mercaptotetrazole) with a copper surface has been studied by accelerated corrosion tests, linear sweep voltammetry (LSV), cyclic voltammetry (CV), Fourier-transform infrared spectroscopy (FT-IR), X-ray photoele...
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| Veröffentlicht in: | Applied surface science 1998-09, Vol.135 (1-4), p.307-317 |
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| container_title | Applied surface science |
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| creator | Ye, X.R Xin, X.Q Zhu, J.J Xue, Z.L |
| description | The chemical nature of the coordination compound film formed by reacting PMTA (1-phenyl-5-mercaptotetrazole) with a copper surface has been studied by accelerated corrosion tests, linear sweep voltammetry (LSV), cyclic voltammetry (CV), Fourier-transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES). These studies show that, in retarding the corrosion of copper substrate, the film is superior to those formed by TTA (tetrazole), BTA (benzotriazole), HBTA (hydroxybenzotriazole), MBT (2-mercaptobenzothiazole), MBI (2-mercaptobenzo-imidazole), 2-AP (2-aminopyrimidine), IBM (imidazole) and chromates. The surface film has been characterized and found to be a polymeric complex of Cu–PMTA. The mechanism for film formation and relationships between this novel film structure and the observed inhibition behavior are discussed. |
| doi_str_mv | 10.1016/S0169-4332(98)00301-8 |
| format | Article |
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These studies show that, in retarding the corrosion of copper substrate, the film is superior to those formed by TTA (tetrazole), BTA (benzotriazole), HBTA (hydroxybenzotriazole), MBT (2-mercaptobenzothiazole), MBI (2-mercaptobenzo-imidazole), 2-AP (2-aminopyrimidine), IBM (imidazole) and chromates. The surface film has been characterized and found to be a polymeric complex of Cu–PMTA. The mechanism for film formation and relationships between this novel film structure and the observed inhibition behavior are discussed.</description><identifier>ISSN: 0169-4332</identifier><identifier>EISSN: 1873-5584</identifier><identifier>DOI: 10.1016/S0169-4332(98)00301-8</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>1-Phenyl-5-mercaptotetrazole ; Applied sciences ; Chemical and electrochemical properties ; Coordination compound films ; Copper surface ; Exact sciences and technology ; Metals. 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These studies show that, in retarding the corrosion of copper substrate, the film is superior to those formed by TTA (tetrazole), BTA (benzotriazole), HBTA (hydroxybenzotriazole), MBT (2-mercaptobenzothiazole), MBI (2-mercaptobenzo-imidazole), 2-AP (2-aminopyrimidine), IBM (imidazole) and chromates. The surface film has been characterized and found to be a polymeric complex of Cu–PMTA. The mechanism for film formation and relationships between this novel film structure and the observed inhibition behavior are discussed.</description><subject>1-Phenyl-5-mercaptotetrazole</subject><subject>Applied sciences</subject><subject>Chemical and electrochemical properties</subject><subject>Coordination compound films</subject><subject>Copper surface</subject><subject>Exact sciences and technology</subject><subject>Metals. Metallurgy</subject><subject>Other surface treatments</subject><subject>Production techniques</subject><subject>Surface treatment</subject><issn>0169-4332</issn><issn>1873-5584</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LxDAQhoMouK7-BKEHET1EkyZp05PI4heseFDPIZtMMNI2NekK6683-4FXLzMw87zzMi9Cp5RcUUKr69dcGswZKy8aeUkIIxTLPTShsmZYCMn30eQPOURHKX0SQsu8naDnWQjR-l6PPvSFCd0Qlr0tnG-7VARXUDx8QL9qscAdRKOHMYwwRv0TWig2imGAWKRldNrAMTpwuk1wsutT9H5_9zZ7xPOXh6fZ7RwbVtUjlpoKY6jlvG7ywFmj7ULUlAnDGM0PVFpXHErJnLPNwgotGiMI1RR4TXjJpuh8e3eI4WsJaVSdTwbaVvcQlkmVNa9F2ZAMii1oYkgpglND9J2OK0WJWoenNuGpdTKqkWoTnpJZd7Yz0Mno1kXdG5_-xCUnshIsYzdbDPKz3x6iSsZDb8D6CGZUNvh_jH4BKn2DRA</recordid><startdate>19980901</startdate><enddate>19980901</enddate><creator>Ye, X.R</creator><creator>Xin, X.Q</creator><creator>Zhu, J.J</creator><creator>Xue, Z.L</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SE</scope><scope>8BQ</scope><scope>8FD</scope><scope>H8G</scope><scope>JG9</scope></search><sort><creationdate>19980901</creationdate><title>Coordination compound films of 1-phenyl-5-mercaptotetrazole on copper surface</title><author>Ye, X.R ; Xin, X.Q ; Zhu, J.J ; Xue, Z.L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-8a15cc1d4479367fdcadb57135c3310036aa64e283ffd9bd5a59c501a1e470423</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>1-Phenyl-5-mercaptotetrazole</topic><topic>Applied sciences</topic><topic>Chemical and electrochemical properties</topic><topic>Coordination compound films</topic><topic>Copper surface</topic><topic>Exact sciences and technology</topic><topic>Metals. Metallurgy</topic><topic>Other surface treatments</topic><topic>Production techniques</topic><topic>Surface treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ye, X.R</creatorcontrib><creatorcontrib>Xin, X.Q</creatorcontrib><creatorcontrib>Zhu, J.J</creatorcontrib><creatorcontrib>Xue, Z.L</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Corrosion Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><jtitle>Applied surface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ye, X.R</au><au>Xin, X.Q</au><au>Zhu, J.J</au><au>Xue, Z.L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coordination compound films of 1-phenyl-5-mercaptotetrazole on copper surface</atitle><jtitle>Applied surface science</jtitle><date>1998-09-01</date><risdate>1998</risdate><volume>135</volume><issue>1-4</issue><spage>307</spage><epage>317</epage><pages>307-317</pages><issn>0169-4332</issn><eissn>1873-5584</eissn><abstract>The chemical nature of the coordination compound film formed by reacting PMTA (1-phenyl-5-mercaptotetrazole) with a copper surface has been studied by accelerated corrosion tests, linear sweep voltammetry (LSV), cyclic voltammetry (CV), Fourier-transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES). 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| issn | 0169-4332 1873-5584 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | 1-Phenyl-5-mercaptotetrazole Applied sciences Chemical and electrochemical properties Coordination compound films Copper surface Exact sciences and technology Metals. Metallurgy Other surface treatments Production techniques Surface treatment |
| title | Coordination compound films of 1-phenyl-5-mercaptotetrazole on copper surface |
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