Chromium nitrides (CrN, Cr2N) from solid state metathesis reactions : effects of dilution and nitriding reagent

The solid state metathesis (SSM) reaction of CrCl sub 3 with Li sub 3 N in a sealed evacuated Pyrex ampoule at 445 deg C produces a propagation wave and enables phase pure Cr sub 2 N to be isolated. The SSM reaction of CrCl sub 2 and Mg sub 3 N sub 2 at 350-500 deg C with dilutant MgCl sub 2 under s...

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Veröffentlicht in:	Journal of materials chemistry 1998, Vol.8 (8), p.1875-1880
Hauptverfasser:	AGUAS, M. D, NARTOWSKI, A. M, PARKIN, I. P, MACKENZIE, M, CRAVEN, A. J
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Elements and non-metal compounds (oxides, hydroxides, hydrides, sulfides, carbides, ...) Exact sciences and technology Inorganic chemistry and origins of life Preparations and properties
Online-Zugang:	Volltext
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