Classification of the asphalts and their source rock from the Dead Sea Basin (Israel): the asphaltene/kerogen vanadyl porphyrins

The asphaltenes of the asphalts from the Dead Sea Basin were examined for the occurrence of vanadyl porphyrins. These examinations demonstrate that the asphalts fall into two broad class types: one which exhibits a relatively high vanadyl porphyrins content (>300 ppm), and the other characterized...

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Veröffentlicht in:Fuel (Guildford) 1998-12, Vol.77 (15), p.1769-1776
Hauptverfasser: Premović, Pavle I, Tonsa, Ivana R, Pavlović, Mirjana S, Liliana López, LoMonaco, Salvador
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container_end_page 1776
container_issue 15
container_start_page 1769
container_title Fuel (Guildford)
container_volume 77
creator Premović, Pavle I
Tonsa, Ivana R
Pavlović, Mirjana S
Liliana López
LoMonaco, Salvador
description The asphaltenes of the asphalts from the Dead Sea Basin were examined for the occurrence of vanadyl porphyrins. These examinations demonstrate that the asphalts fall into two broad class types: one which exhibits a relatively high vanadyl porphyrins content (>300 ppm), and the other characterized with no vanadyl porphyrins (
doi_str_mv 10.1016/S0016-2361(98)00100-8
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These examinations demonstrate that the asphalts fall into two broad class types: one which exhibits a relatively high vanadyl porphyrins content (&gt;300 ppm), and the other characterized with no vanadyl porphyrins (&lt;10 ppm). It is concluded that these asphalts belong to two distinct types and have separate origins. The kerogens isolated from the petroleum-source rock of the Dead Sea Basin were also analyzed. Two genetic types of kerogen appeared to exist: a marine one highly enriched with these pigments and a terrestrial one with no vanadyl porphyrins. For comparison, the asphaltenes of typical asphaltic crude oils from Western Venezuela and kerogen from their La Luna source rock were also examined. Previous detailed geochemical studies [1]indicated that the La Luna kerogen is derived from marine organic matter source. These materials have higher concentrations of vanadyl porphyrins than the Dead Sea asphaltenes and kerogens are enriched with these compounds. 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Analysis and characteristics</topic><topic>Crude oil, natural gas and petroleum products</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Fuels</topic><topic>kerogen</topic><topic>vanadyl porphyrins</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Premović, Pavle I</creatorcontrib><creatorcontrib>Tonsa, Ivana R</creatorcontrib><creatorcontrib>Pavlović, Mirjana S</creatorcontrib><creatorcontrib>Liliana López</creatorcontrib><creatorcontrib>LoMonaco, Salvador</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology &amp; Engineering</collection><collection>Engineering Research Database</collection><jtitle>Fuel (Guildford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Premović, Pavle I</au><au>Tonsa, Ivana R</au><au>Pavlović, Mirjana S</au><au>Liliana López</au><au>LoMonaco, Salvador</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Classification of the asphalts and their source rock from the Dead Sea Basin (Israel): the asphaltene/kerogen vanadyl porphyrins</atitle><jtitle>Fuel (Guildford)</jtitle><date>1998-12-01</date><risdate>1998</risdate><volume>77</volume><issue>15</issue><spage>1769</spage><epage>1776</epage><pages>1769-1776</pages><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>The asphaltenes of the asphalts from the Dead Sea Basin were examined for the occurrence of vanadyl porphyrins. These examinations demonstrate that the asphalts fall into two broad class types: one which exhibits a relatively high vanadyl porphyrins content (&gt;300 ppm), and the other characterized with no vanadyl porphyrins (&lt;10 ppm). It is concluded that these asphalts belong to two distinct types and have separate origins. The kerogens isolated from the petroleum-source rock of the Dead Sea Basin were also analyzed. Two genetic types of kerogen appeared to exist: a marine one highly enriched with these pigments and a terrestrial one with no vanadyl porphyrins. For comparison, the asphaltenes of typical asphaltic crude oils from Western Venezuela and kerogen from their La Luna source rock were also examined. Previous detailed geochemical studies [1]indicated that the La Luna kerogen is derived from marine organic matter source. These materials have higher concentrations of vanadyl porphyrins than the Dead Sea asphaltenes and kerogens are enriched with these compounds. Our results strengthen the potential of vanadyl porphyrins of both petroleum asphaltenes and source-rock kerogen for use in genetic and correlation studies.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0016-2361(98)00100-8</doi><tpages>8</tpages></addata></record>
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source ScienceDirect Journals (5 years ago - present)
subjects Applied sciences
asphalt
Constitution and properties of crude oils, shale oils, natural gas and bitumens. Analysis and characteristics
Crude oil, natural gas and petroleum products
Energy
Exact sciences and technology
Fuels
kerogen
vanadyl porphyrins
title Classification of the asphalts and their source rock from the Dead Sea Basin (Israel): the asphaltene/kerogen vanadyl porphyrins
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